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Synthetic transformations of higher terpenoids: XXIX. Gold catalyzed cycloisomerization of propargylaminomethyl substituted and propargyloxymethyl substituted furanolabdanoids

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Abstract

16-Propargylaminomethyl substituted and 16-propargyloxymethyl substituted furanolabdanoids were synthesized, which under the action of AuCl3 in acetonitrile underwent cycloisomerization forming 7-hydroxyisoindolines or 7-hydroxydihydroisobenzofurans substituted by a terpenoid fragment.

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Correspondence to Yu. V. Kharitonov.

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Original English Text © Yu.V. Kharitonov, E.E. Shults, M.M. Shakirov, I.Yu. Bagryanskaya, G.A. Tolstikov, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 8, pp. 1085–1092.

For Communication XXVIII, see [1]

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Kharitonov, Y.V., Shults, E.E., Shakirov, M.M. et al. Synthetic transformations of higher terpenoids: XXIX. Gold catalyzed cycloisomerization of propargylaminomethyl substituted and propargyloxymethyl substituted furanolabdanoids. Russ J Org Chem 48, 1081–1089 (2012). https://doi.org/10.1134/S1070428012080088

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  • DOI: https://doi.org/10.1134/S1070428012080088

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