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Condensation of Trifluoromethanesulfonamide with Paraformaldehyde and Oxamide

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Abstract

Depending on the conditions, three-component condensation of trifluoromethanesulfonamide with paraformaldehyde and oxamide led to the formation of linear products, N-mono- and N,N’-bis[(trifluoromethylsulfonyl)aminomethyl]oxamide, bis[(trifluoromethylsulfonyl)aminomethyl] ethanedioate, as well as of hydrolysis and cyclization product, N-(4,5-dioxo-1,3-oxazolidin-3-ylmethyl)trifluoromethanesulfonamide.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    V. I. Meshcheryakov, M. Yu. Moskalik & B. A. Shainyan

  2. Chemisches Institut der Universität Potsdam P.O. Box, 691553, Potsdam, D-14415, Germany

    I. Starke

Authors
  1. V. I. Meshcheryakov
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  2. M. Yu. Moskalik
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  3. I. Starke
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  4. B. A. Shainyan
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Corresponding author

Correspondence to B. A. Shainyan.

Additional information

Original Russian Text © V.I. Meshcheryakov, M.Yu. Moskalik, I. Starke, B.A. Shainyan, 2010, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46 No. 10, pp. 1467–1471.

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Meshcheryakov, V.I., Moskalik, M.Y., Starke, I. et al. Condensation of Trifluoromethanesulfonamide with Paraformaldehyde and Oxamide. Russ J Org Chem 46, 1471–1475 (2010). https://doi.org/10.1134/S1070428010100052

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  • DOI: https://doi.org/10.1134/S1070428010100052

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