Abstract
Synthesis of 2-hydroxy(methoxy)-4,4′-biphenyldicarboxylic acids was developed. Based on their reactions with o-aminophenols we prepared for the first time 4,4′-bis[5-alkyl(aryl)benzoxazol-2-yl]-2-hydroxy-(alkoxy)biphenyls, which might be of interest as luminescent dyes. Hydroxy compounds in a salt form possess abnormally high Stokes shift.
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Krasovitskii, B.M. and Bolotin, B.M., Organicheskie lyuminofory (Organic Luminophores), Moscow: Khimiya, 1984, p. 202.
Ol’khovik, V.K., Kalechits, G.V., and Agabekov, V.E., Vestsi Natio. Akad. Nauk of Belarus, Ser.Khim., 2002, p. 113.
Reinehr, D., Eckhardt, C., Kasching, J., and Weber, K., EPV Patent 321715, 1989; Chem. Abstr., 1989, vol. 111, 235650m.
Suzuki, T., Takahashi, H., Nishida, J., and Takashi, T., Chem. Commun. Chem. Soc., 1998, p. 1331.
Gelisser, C., Bormans, G. and de Groot, T. J. Labele, Compounds and Radiopharm., 1999, vol. 42, p. 5185.
Clemens, A.H., WIPO Patent 9411485, 1995; Chem. Abstr., 1995, vol. 122, 242797v.
Dell’Armo, L.A. and Lala, R.J., EPV Patent 368383, 1990; Chem. Abstr., 1990, vol. 113, 174513m.
Leaver, I.H. and Milligan, B., Dyes and Pigments, 1984, vol. 5, p. 109.
Ol’khovik, V.K., Kalechits, G.V., Matveenko, Yu.V., Pap, A.A., Zenyuk, A.A., and Erdman, A.A., RB Patent 5137, 2003, Ref. Zh. Khim., 2004, 19N195P.
Ol’khovik, V.K., Matveenko, Yu.V., Kalechits, G.V., Pap, A.A., and Zenyuk, A.A., RB Patent 6194, 2004.
Bassignana, P., Cogrossi, C., Gandino, M., and Merli, P., Spectr. Acta, 1965, vol. 21, p. 605.
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Original Russian Text © V.K. Ol’khovik, Yu.V. Matveenko, G.V. Kalechits, A.A. Pap, A.A. Zenyuk, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 8, pp. 1185–1189.
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Ol’khovik, V.K., Matveenko, Y.V., Kalechits, G.V. et al. Synthesis and properties of 4,4′-bis[5-alkyl(aryl)benzoxazol-2-yl]-2-hydroxy(alkoxy)biphenyls. Russ J Org Chem 42, 1164–1168 (2006). https://doi.org/10.1134/S1070428006080100
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DOI: https://doi.org/10.1134/S1070428006080100