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Mechanism of lubricating action of polyphosphate and heteropolyphosphate additives in tribosystems

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Abstract

The phase diagrams of the Zn(PO3)2–Ca(PO3)2 and Zn(PO3)2–Ni(PO3)2 systems were studied, and the double phosphates CaZn(PO3)4 and NiZn(PO3)4 were allocated. The anions of these compounds are chain polyphosphates with PO4 tetrahedra in the period of identity. The structures and mechanism of the action of these compounds as additives to lubricants were described using quantum-chemical analysis. Improvement of the physicochemical and tribotechnical characteristics of lubricating materials containing these phosphates compared to the traditionally used lubricating materials was confirmed in tribotechnical tests.

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References

  1. Ludema, K.C., Friction, Wear, Lubrication: A Textbook in Tribology, CRC, 1996.

    Book  Google Scholar 

  2. Rudnick, L.R., Lubricant Additives: Chemistry and Applications, CRC, 2009.

    Book  Google Scholar 

  3. Ermakov, S.F., J. Friction Wear, 2012, vol. 33, pp. 72–87.

    Article  Google Scholar 

  4. Ermakov, S.F., J. Friction Wear, 2012, vol. 33, pp. 217–223.

    Article  Google Scholar 

  5. Wan, S., Tieu, A.K., Xia, Y., et al. Tribol. Int., 2016, vol. 102, pp. 620–635.

    Article  CAS  Google Scholar 

  6. Kolesnikov, V.I., Migal, Yu.F., Savenkova, M.A., and Mizhiritskaya, S.N., J. Friction Wear, 2009, vol. 30, pp. 404–410.

    Article  Google Scholar 

  7. te Velde, G., Bickelhaupt, F.M., van Gisbergen, S.J.A., et al., J. Comput. Chem., 2001, vol. 22, no. 6, pp. 931–967.

    Article  Google Scholar 

  8. Kajdas, C., Harvey, S.S.K., and Wilusz, E., Encyclopedia of Tribology, New York: Elsevier, 1990.

    Google Scholar 

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Authors and Affiliations

  1. Rostov State Transport University, Rostov-on-Don, 344038, Russia

    V. I. Kolesnikov, M. A. Savenkova, Yu. F. Migal, N. A. Myasnikova & D. N. Shishiyanu

Authors
  1. V. I. Kolesnikov
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  2. M. A. Savenkova
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  3. Yu. F. Migal
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  4. N. A. Myasnikova
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  5. D. N. Shishiyanu
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Corresponding author

Correspondence to Yu. F. Migal.

Additional information

Original Russian Text © V.I. Kolesnikov, M.A. Savenkova, Yu.F. Migal, N.A. Myasnikova, D.N. Shishiyanu, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 5, pp. 609−619.

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Kolesnikov, V.I., Savenkova, M.A., Migal, Y.F. et al. Mechanism of lubricating action of polyphosphate and heteropolyphosphate additives in tribosystems. Russ J Appl Chem 90, 743–753 (2017). https://doi.org/10.1134/S1070427217050135

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  • DOI: https://doi.org/10.1134/S1070427217050135

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