Abstract
The consistency of the suggested mechanisms of formic acid formation with the composition of products formed in the industrial process of cyclohexane oxidation was examined. The role of formic acid in the formation of cyclohexyl esters of mono-and dicarboxylic acids was elucidated.
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References
Berezin, I.V., Denisov, E.T., and Emanuel’, N.M., Okislenie tsiklogeksana (Oxidation of Cyclohexane), Moscow: Mosk. Gos. Univ., 1962.
Proizvodstvo tsiklogeksanona i adipinovoi kisloty okisleniem tsiklogeksana (Production of Cyclohexanone and Adipic Acid by Oxidation of Cyclohexane), Furman, M.S. and Gol’dman, A.M., Eds., Moscow: Khimiya, 1967.
Denisov, E.T., Mitskevich, N.I., and Agabekov, V.E., Mekhanizm zhidkofaznogo okisleniya kislorodsoderzhashchikh soedinenii (Mechanism of Liquid-Phase Oxidation of Oxygen-Containing Compounds), Minsk: Nauka i Tekhnika, 1975.
Perkel’, A.L., Voronina, S.G., and Freidin, B.G., Usp. Khim., 1994, vol. 63, no. 9, pp. 793–796.
Freidin, B.G. and Perkel’, A.L., Zh. Prikl. Khim., 1980, vol. 53, no. 4, pp. 861–866.
Perkel, A.L., Buneeva, E.I., and Voronina, S.G., Oxid. Commun., 2000, vol. 23, no. 1, pp. 12–28.
Perkel’, A.L., Freidin, B.G., Neginskaya, R.V., et al., Zh. Prikl. Khim., 1985, vol. 58, no. 7, pp. 1572–1577.
Kotel’nikova, T.S., Vdovenko, O.V., Voronina, S.G., and Perkel’, A.L., Zh. Anal. Khim., 2006, vol. 61, no. 2, pp. 1–6.
Perkel’, A.L. and Voronina, S.G., Zh. Anal. Khim., 1998, vol. 53, no. 4, pp. 343–363.
Perkel’, A.L., Voronina, S.G., and Perkel’, R.L., Zh. Anal. Khim., 1991, vol. 46, no. 11, pp. 2283–2286.
Smith, H.A., C. R. Acad. Sci. Paris, 1964, vol. 61, pp. 254–260.
Loury, M., J. Am. Chem. Soc., 1939, vol. 258, no. 1, pp. 238–239.
Valters, R.E., Kol’chato-tsepnaya izomeriya v organicheskoi khimii (Ring-Chain Isomerism in Organic Chemistry), Riga: Zinatne, 1978.
Yatchishin, I.I., Romanyuk, O.I., and Marshalok, G.A., Abstracts of Papers, Vsesoyuznaya konferentsiya “Kinetika radikal’nykh zhidkofaznykh reaktsii” (All-Union Conf. “Kinetics of Radical Liquid-Phase Reactions”), Yaroslavl, 1990, p. 115.
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Original Russian Text © T.S. Kotel’nikova, S.G. Voronina, A.L. Perkel’, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 3, pp. 424–428.
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Kotel’nikova, T.S., Voronina, S.G. & Perkel’, A.L. Formation of formic acid and cyclohexyl formate in oxidation of cyclohexane. Russ J Appl Chem 79, 416–420 (2006). https://doi.org/10.1134/S1070427206030165
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DOI: https://doi.org/10.1134/S1070427206030165