Abstract
General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl)piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1-ynyl]mercury. Conditions of these reactions were optimized.
Similar content being viewed by others
References
Badanyan, Sh.O., Chobanyan, Zh.A., Tirakyan, M.R., and Danielyan, A.O., Chem. Heterocycl. Compd., 1998, vol. 34, no. 7, p. 781. doi 10.1007/BF02251682
Hobosyan, N.G., Balyan, K.V., Nersisyan, H.S., Sargsyan, H.B, Chobanyan, Zh.A., Russ. J. Gen. Chem., 2016, vol. 86, p. 1011. doi 10.1134/S1070363216050042
Balyan, K.V., Gendzhoyan, L.M., Akopyan, B.B., Hobosyan, N.G., and Chobanyan, Zh.A., Russ. J. Gen. Chem., 2014, vol. 84, no. 11, p. 2098. doi 10.1134/S1070363214110097
Müller, T.E., Hultzsch, K.C., Yus, M., Foubelo, F., and Tada, M., Chem. Rev., 2008, vol. 108, no. 9, p. 3795. doi 10.1021/cr0306788
Fäcke, T. and Berger, S., J. Organomet. Chem., 1994, vol. 471, nos. 1–2, p. 35. doi 10.1016/0022-328X(94) 88102-2
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.G. Hobosyan, K.V. Balyan, A.L. Petrosyan, S.A. Hovakimyan, Zh.A. Chobanyan, R.S. Nersisyan, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 1, pp. 33–36.
Rights and permissions
About this article
Cite this article
Hobosyan, N.G., Balyan, K.V., Petrosyan, A.L. et al. Alkylation of 1-(prop-2-ynyl)piperidine with СН-acids in ihe presence of mercury(II) acetate. Russ J Gen Chem 87, 29–32 (2017). https://doi.org/10.1134/S1070363217010066
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363217010066