Abstract
Reaction of 1-germatranol hydrate with carboxylic acids RCOOH (R = ClCH2, PhCH=CH, Ph, 2-FC6H4, 3-BrC6H4, 3-HOC6H4, 3-EtOC6H4) in protic (CH3OH, iso-C5H11OH) and aprotic polar solvent (CH3CN) is studied. 1-Acyloxygermatranes RC(O)OGe(OCH{in2}CH{in2}){in3}N are formed in yields from 11 to ~100 % depending on the nature of the acid, solvent, duration of the process and the method of its completion. The reaction is the most effective in acetonitrile. Its topochemical completion (heating of the reaction residue in a vacuum) increases the yield of 1-acyloxygermatranes.
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Original Russian Text © V.P. Baryshok, N.T.Z. Le, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 12, pp. 2016–2021.
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Baryshok, V.P., Le, N.T.Z. Reaction of 1-germatranol hydrate with carboxylic acids. Russ J Gen Chem 85, 2748–2753 (2015). https://doi.org/10.1134/S1070363215120154
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DOI: https://doi.org/10.1134/S1070363215120154