Skip to main content
SpringerLink
Log in

Optical and electrochemical properties of cyclometallated Rh(III) and Pd(II) complexes based on phenyl-substituted pyrazole, pyridine, and pyrimidine with ethylenediamine, 2,2′-bipyridine, and 1,10-phenanthroline

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Electrochemical and optical properties of cyclometallated Rh(III) and Pd(II) complexes based on phenyl-substituted pyrazole, pyridine, and pyrimidine with ethylenediamine, 2,2′-bipyridine, and 1,10-phenanthroline chelating ligands were investigated. One-electron reduction waves of the complexes were assigned to ligand-centered processes of electron transfer on π* orbitals of heterocyclic chelating and cyclometallated ligands, whereas irreversible oxidation waves, to the processes involving a mixed phenyl-metal π/d orbital. The long-wave absorption band results from by the spin-allowed optical transition between π/d-HOMO and a π* orbital of a cyclometallated ligand. The character of the optical transition responsible for low-temperature (77 K) phosphorescence of the complexes is defined by the ratio of the energy gap between π* orbitals of chelating and cyclometallated ligands and by the energy of the singlet-triplet splitting of electron-excited states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Koo, C.-K., Wong, K.-L., Man, C.W.-Y., Lam, Y.-W., So, L.K.-Y., Tam, H.-L., Tsao, S.-W., Cheah, K.-W., Lau, K.-C., Yang, Y.-Y., Chen, J.-C., and Lam, M.H.-W., Inorg. Chem., 2009, vol. 48, no. 3, p. 872.

    Article  CAS  Google Scholar 

  2. Borisov, S.M. and Climant, I., Anal. Chem., 2007, vol. 79, no. 19, p. 7501.

    Article  CAS  Google Scholar 

  3. Williams, J.A.G., Delay, S., Rochester, D.L., and Murphy, L., Coord. Chem. Rev., 2008, vol. 252, nos. 23–24, p. 2596.

    Google Scholar 

  4. Dupont, J., Consorti, C.S., and Spencer, J., Chem. Rev., 2005, vol. 105, no. 6, p. 2527.

    Article  CAS  Google Scholar 

  5. Aiello, I., Dattilo, D., Ghedini, M., and Golemme, A., J. Am. Chem. Soc., 2001, vol. 123, no. 23, p. 5598.

    Article  CAS  Google Scholar 

  6. Chakraborty, S., Wadas, T.J., Hester, H., Schmehl, R., and Eisenberg, R., Inorg. Chem., 2005, vol. 44, no. 20, p. 6865.

    Article  CAS  Google Scholar 

  7. Thompson, M.E., Djurovich, P.I., Barlow, S., and Marder, S., Comprehensive Organometal. Chem. III., 2007, vol. 12, p. 101.

    Article  Google Scholar 

  8. DeArmond, M. and Carlin, C., Coord. Chem. Rev., 1985, vol. 63, p. 325.

    Google Scholar 

  9. Koopmans, T., Physics, 1933, vol. 1, no. 1, p. 104.

    CAS  Google Scholar 

  10. Maestri, M., Sandrini, D., Balzani, V., Maeder, U., and von Zelewsky, A., Inorg. Chem., 1987, vol. 26, no. 8, p. 1323.

    Article  CAS  Google Scholar 

  11. Demas, J.N., J. Chem. Educ., 1983, vol. 60, no. 10, p. 803.

    Article  CAS  Google Scholar 

  12. Gas, B., Klima, J., Zalis, S., and Vlcek, A.A., J. Electroanal. Chem., 1987, vol. 222, no. 1, p. 161.

    Article  CAS  Google Scholar 

  13. Sandrini, D., Maestri, M., Ciano, M., Maeder, U., and von Zelewsky, A., Helv. Chim. Acta, 1990, vol. 73, no. 5, p. 1306.

    Article  CAS  Google Scholar 

  14. Maestri, M., Sandrini, D., Balzani, V., Maeder U., and von Zelewsky, A., Inorg. Chem., 1987, vol. 26, no. 8, p. 1323.

    Article  CAS  Google Scholar 

  15. Hill, R.H. and Puddephatt, R.J., J. Am. Chem. Soc., 1985, vol. 107, no. 5, p. 1218.

    Article  CAS  Google Scholar 

  16. Ohsawa, Y., Sprouse, S., King, K.A., DeArmond, M.K., Hanck, K.W., and Watts, R.J., J. Phys. Chem., 1987, vol. 91, no. 5, p. 1047.

    Article  CAS  Google Scholar 

  17. Steel, P.J., J. Organomet. Chem., 1991, vol. 408, no. 3, p. 395.

    Article  CAS  Google Scholar 

  18. Calagero, G., Giuffrida, G., Seroni, S., Ricevuto, V., and Campagna, S., Inorg. Chem., 1995, vol. 34, no. 3, p. 541.

    Article  Google Scholar 

  19. Su, L., Yu, Y.C., Tseng, M.C., Wang, S.P., and Huang, W.L., Dalton Trans., 2007, no. 31, p. 3440.

  20. Lamansky, S., Djurovich, P., Murthy, D., Abdel-Razzaq, F., Lee, H.-F., Adachi, C., Burrows, P.E., Forest, S.R., and Thompson, M.E., J. Am. Chem. Soc., 2001, vol. 123, no. 18, p. 4304.

    Article  CAS  Google Scholar 

  21. Ivanova, E.V., Puzyk, M.V., and Balashev, K.P., Zh. Obshch. Khim., 2009, vol. 79, no. 10, p. 1600.

    Google Scholar 

  22. Busby, M., Matousek, P., Towrie, M., Clark, I.P., Motevalli, M., Hartl, F., and Vlcek, A., Inorg. Chem., 2004, vol. 43, no. 14, p. 4523.

    Article  CAS  Google Scholar 

  23. Barigelletti, F., Sandrini, D., Maestri, M., Balzani, V., von Zelewsky A., Chassot, L., Joliet, P., and Maeder, U., Inorg. Chem., 1988, vol. 27, no. 20, p. 3644.

    Article  CAS  Google Scholar 

  24. Ivanova, E.V. and Balashev, K.P., Zh. Obshch. Khim., 2009, vol. 79, no. 10, p. 1749.

    Google Scholar 

  25. Ivanova, E.V. and Balashev, K.P., Zh. Obshch. Khim., 2009, vol. 79, no. 10, p. 1756.

    Google Scholar 

  26. Ivanova, E.V., Puzyk, M.V., and Balashev, K.P., Opt. Spektr., 2009, vol. 106, no. 3, p. 409.

    Google Scholar 

  27. Vasil’ev, V.V., Balashev, K.P., and Shagisultanova, G.A., Opt. Spektr., 1983, vol. 54, no. 5, p. 876.

    Google Scholar 

  28. Vasil’ev, V.V., Balashev, K.P., and Shagisultanova, G.A., Opt. Spektr., 1983, vol. 54, no. 5, p. 876.

    Google Scholar 

  29. Kotlyar, V.S. and Balashev, K.P., Elektrokhim., 1996, vol. 32, no. 11, p. 1358.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Herzen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    K. P. Balashev, M. V. Puzyk & E. V. Ivanova

Authors
  1. K. P. Balashev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Puzyk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. P. Balashev.

Additional information

Original Russian Text © K.P. Balashev, M.V. Puzyk, E.V. Ivanova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 7, pp. 1199–1207.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Balashev, K.P., Puzyk, M.V. & Ivanova, E.V. Optical and electrochemical properties of cyclometallated Rh(III) and Pd(II) complexes based on phenyl-substituted pyrazole, pyridine, and pyrimidine with ethylenediamine, 2,2′-bipyridine, and 1,10-phenanthroline. Russ J Gen Chem 81, 1547–1554 (2011). https://doi.org/10.1134/S1070363211070231

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211070231

Keywords

Search

Navigation