Skip to main content
SpringerLink
Log in

Coherent molecular motion in aquatic environment. Extraction of correlation from noise

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Molecular dynamics simulation of liquid water and system “argon-thin water film” has been performed. In was shown that time dependence of distances between oxygen atoms of water molecules, connected by hydrogen bonds, looks like random noise and these molecules are doomed to move concertedly. The average distance between the argon atoms dissolved in water is retained for some time, so the argon atoms included in the hydrogen bond networks, but not capable to participate in hydrogen bonds are involved in concerted motions. The problem of revealing the correlations in the motion of molecules and atoms is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bernal, J.D. and Fowler, R.H., J. Chem. Phys., 1933, vol. 1, pp. 515–548.

    Article  CAS  Google Scholar 

  2. Gorbunova, K.M., Private Message.

  3. Rodnikova, M.N., J. Phys. Chem., 1991, vol. 67, no. 2, pp. 275–280.

    Google Scholar 

  4. Rodnikova, M.N. and Chumaevskii, N.A., J. Struct. Chem., 2006, pp. 154–160.

  5. Malenkov, G.G., Ibid., 2006, vol. 47, pp. 5–35.

    Article  Google Scholar 

  6. Malenkov, G.G., Tytik, D.L., and Zheligovskaya, E.A., J. Mol. Liquids, 2003, vol. 106, nos. 2–3, pp. 179–198.

    Article  CAS  Google Scholar 

  7. Holz, M. and Heil, S.R., Sacco A. Phys. Chem. Chem. Phys., 2000, vol. 2, pp. 4740–4742.

    CAS  Google Scholar 

  8. Voda i vodnye rastvory pri temperaturakh ne nizhe 0°C (Water and Water Solutions at Temperature Lower than 0°C), Frank, F., Ed., Kiev: Naukova Dumka, 1985.

    Google Scholar 

  9. Malenkov, G.G., Tytik, D.L, Zand heligovskaya, E.A., J. Mol. Liquids, 1999, vol. 82, no. 1, pp. 27–38.

    Article  CAS  Google Scholar 

  10. Voloshin, V.P. and Naberukhin, Yu.I., J. Struct. Chem., 2009, vol. 50, no. 1.

  11. Voloshin, V.P., Malenkov, G.G., and Naberukhin, Yu.I., Ibid., 2007, vol. 48, no. 6, pp. 1133–1138.

    Article  Google Scholar 

  12. Malenkov, G., Naberukhin, Yu., and Voloshin, V., Struct. Chem., 2009, in press.

  13. Timashev, S.F., Flikker-shumovaya spektroskopiya: informatsiya v khaoticheskikh signalakh (Flicker Noice Spectroscopy: Information about Chaotic Signals), Moscow: Fizmatlit, 2007.

    Google Scholar 

  14. Malenkov, G.G. and Titik, D.L., Izv. Ross. Akad. Nauk, Ser. Fiz., 2000, vol. 64, no. 8, pp. 1469–1474.

    CAS  Google Scholar 

  15. Bulavin, L.A., Lokotosh, T.V., and Malomuzh, N.P., J. Liquids, 2008, vol. 137, no. 1, pp. 1–24.

    Article  CAS  Google Scholar 

  16. Voloshin, V.P., Zheligovskaya, E.A., Malenkov, G.G., Naberukhin, Yu.I., and Titik, D.L,. Ross. Khim. Zh. (Zh. Ross. Khim. O-va im. Mendeleeva), 2001, vol. 45, no. 3, pp. 31–37.

    CAS  Google Scholar 

  17. Manakov, A.Yu. and Dyadin, Yu.A., Ibid., 2003, vol. 47, no. 3, pp. 28–41.

    Google Scholar 

  18. Malenkov, G.G. and Zheligovskaya, E.A., J. Inclusion Phenomena and Macrocyclic Chem., 2004, vol. 48, no. 1, pp. 45–54.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Malenkov

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, ul. Institutskaya 3, Novosibirsk, 630090, Russia

    Yu. I. Naberukhin & V. P. Voloshin

Authors
  1. G. G. Malenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. I. Naberukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Voloshin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. G. Malenkov.

Additional information

Original Russian Text © G.G. Malenkov, Yu.I. Naberukhin, V.P. Voloshin, 2009, published in Rossiiskii Khimicheskii Zhurnal, 2009, Vol. 53, No. 6, pp. 25–32.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Malenkov, G.G., Naberukhin, Y.I. & Voloshin, V.P. Coherent molecular motion in aquatic environment. Extraction of correlation from noise. Russ J Gen Chem 81, 191–199 (2011). https://doi.org/10.1134/S1070363211010361

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211010361

Keywords

Search

Navigation