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A new route to 1-chlorosilatrane

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Abstract

A method for the synthesis of 1-chlorosilatrane by the reaction of organyltrichlorosilanes RSiCl3 (R = Vin, Ph) and tetrachlorosilane with triethanolamine or its hydrochloride was developed. This simple and economical method allows obtaining 1-chlorosilatrane in 60% yield.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. G. Voronkov & G. A. Kuznetsova

  2. Irkutsk State Technical University, Irkutsk, Russia

    V. P. Baryshok

Authors
  1. M. G. Voronkov
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  2. G. A. Kuznetsova
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  3. V. P. Baryshok
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Correspondence to M. G. Voronkov.

Additional information

Original Russian Text © M.G. Voronkov, G.A. Kuznetsova, V.P. Baryshok, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 10, pp. 1615–1617.

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Voronkov, M.G., Kuznetsova, G.A. & Baryshok, V.P. A new route to 1-chlorosilatrane. Russ J Gen Chem 80, 1926–1928 (2010). https://doi.org/10.1134/S1070363210100075

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  • DOI: https://doi.org/10.1134/S1070363210100075

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