Abstract
The fact was established that the pyrolysis of gaseous iodomethanes RI yields methane and non traces of recombination products R2. A pyrolysis mechanism was proposed and rate constants of limiting stages of the pyrolysis of iodomethane, trideuteroiodomethane, and diiodomethane over the range of 500–1500 K were determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Skorobogatov, G.A., Dymov, B.P., Lebedev, V.N., and Khripun, V.K., Kinet. Katal., 1987, vol. 28, no. 4, p. 785.
Tedeev, R.S., Dymov, B.P., and Skorobogatov, G.A., Vestn. Len. Gos. Univ., Ser. 4, 1989, issue 1, no. 4, p. 37.
Skorobogatov, G.A., Dymov, B.P., and Tedeev, R.S., Zh. Obshch. Khim., 1991, vol. 61, no. 1, p. 178.
Skorobogatov, G.A., Dymov, B.P., Khripun, V.K., Kinet. Katal., 1991, vol. 32, no. 2, p. 252.
Skorobogatov, G.A., Rebrova, A.G., and Khripun, V.K., Zh. Obshch. Khim., 2005, vol. 75, no. 10, p. 1600.
Skorobogatov, G.A., Khripun, V.K., and Rebrova, A.G., Kinet. Katal., 2008, vol. 49, no. 4, p. 489.
Ogg, R.A., J. Am. Chem. Soc., 1934, vol. 56, p. 526.
Sullivan, J.H., J. Phys. Chem., 1961, vol. 65, no. 5, p. 722.
Gurvich, L.V., Veits, I.V., Medvedev, V.A., Khachkuruzov, G.A., Yungman, V.S., Bergman, G.A., Baibuz, V.F., Iorish, V.S., Yurkov, G.N., Gorbov, S.I., Kuratova, L.F., Rtishcheva, N.P., Przhevalskii, I.N., Zitserman, V.J., Leonidov, V.Ya., Ezhov, Yu.S., Tomberg, S.E., Nazarenko, I.I., Rogatskii, A.L., Dorofeeva, O.V., and Demidova, M.S., Termodinamicheskie svoistva individual’nykh veshchestv (Thermodynamic Properties of Individual Substances), Moscow: Nauka, 1978, vol. 2, issue 1.
Skorobogatov, G.A., Slesar’, O.N., and Seleznev, V.G., Dokl. Akad. Nauk SSSR, 1977, vol. 237, p. 889.
Calvert, J.G. and Pitts, J.N., Photochemistry, New York: Wiley, 1965.
Scheld, H.A., Furlan, A., and Huber, J.R., J. Chem. Phys., 1999, vol. 111, no. 3, p. 923.
Skorobogatov, G.A., Meilakhs, A.G., Pogosyan, J.I., and Khripun, V.K., Zh. Obshch. Khim., 2002, vol. 72, no. 8, p. 1354.
Sulzer, P. and Wieland, K., Helv. Phys. Acta, 1962, vol. 25, p. 653.
Tellinghuisen, J., J. Chem. Phys., 1973, vol. 58, p. 2821.
Zalesskii, V.Yu., Opt. Spektrosk., 1989, vol. 66, no. 2, p. 296.
Elokhin, V.A. and Ivanov, V.S., Zh. Prikl. Spektrosk., 1980, vol. 33, no. 4, p. 759.
Nefedov, V.D. and Skorobogatov, G.A., Radiokhim., 1961, vol. 3, no. 2, p. 229.
Dymov, B.P., Skorobogatov, G.A., and Chuikov-Ru, E.P., Zh. Obshch. Khim., 2004, vol. 74, no. 11, p. 1812.
Seetula, J.A., Russel, J.J., and Gutman, D., J. Am. Chem. Soc., 1990, vol. 112, no. 4, p. 1347.
Saito, K., Tahara, H., Kondo, O., Yokubo, T., Higashihara, T., and Murakami, I., Bull. Chem. Soc. Japan, 1980, vol. 53, p. 1335.
Mintz, K.J. and Le Roy, D.J., Canad. J. Chem., 1978, vol. 56, no. 7, p. 941.
Smith, W.M., J. Chem. Soc., Faraday Trans., 1991, vol. 87, no. 15, p. 2271.
Korol’kov, D.V., Skorobogatov, G.A., Rebrova, A.G., and Baranovskii, V.I., Zh. Obshch. Khim., 2006, vol. 76, no. 2, p. 259.
Denisov, E.T., Sarkisov, O.M., and Liechtenstein, G.I., Khimicheskaya kinetika (Chemical Kinetics), Moscow: Khimiya, 2000.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.A. Skorobogatov, V.K. Khripun, A.G. Rebrova, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 12, pp. 2015–2025.
Rights and permissions
About this article
Cite this article
Skorobogatov, G.A., Khripun, V.K. & Rebrova, A.G. Isothermal pyrolysis of iodomethanes in gases. Russ J Gen Chem 79, 2641–2651 (2009). https://doi.org/10.1134/S1070363209120147
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363209120147