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Synthesis characterization, crystal structures, and antibacterial activity of 8-hydroxyquinoline-coordinated oxidovanadium(V) complexes with tridentate hydrazone ligands

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Abstract

Two new oxidovanadium(V) complexes, [VO(L1)(L)] (I) and [VO(L2)(L)] (II), where L1 and L2 are the dianionic form of N'-(2-hydroxy-5-methoxybenzylidene)pivalohydrazide (H2L1) and N'-(2-hydroxy-3-methoxybenzylidene)pivalohydrazide (H2L2), respectively, and L is the monoanionic form of 8-hydroxyquinoline (HL), were prepared and characterized by elemental analysis, infrared and electronic spectra, and 1H NMR spectra. Structures of the complexes were further confirmed by single crystal X-ray determination (CIF files CCDC nos. 1477854 (I), 1477856 (II)). H2L1 and H2L2 coordinate to the V atoms through the phenolate O, imino N, and enolate O atoms. 8-Hydroxyquinoline coordinates to the V atoms through bidentate ON donor set. The V atoms of the complexes are in octahedral coordination with the oxo group furnished the octahedral geometry. The complexes show effective antibacterial activity against Bacillus subtilis.

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Authors and Affiliations

  1. Key Laboratory of Surface and Interface Science of Henan, School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, 450002, P.R. China

    H. Y. Qian

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  1. H. Y. Qian
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Qian, H.Y. Synthesis characterization, crystal structures, and antibacterial activity of 8-hydroxyquinoline-coordinated oxidovanadium(V) complexes with tridentate hydrazone ligands. Russ J Coord Chem 43, 780–786 (2017). https://doi.org/10.1134/S1070328417110070

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  • DOI: https://doi.org/10.1134/S1070328417110070

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