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Mixed-ligand lanthanide complexes with acylpyrazolones and phosphorus-containing ligands

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Abstract

The reactions of lanthanum acetylacetonate with various phosphorus-containing pesticides, toxic gases, and products of their hydrolysis are modeled by quantum-chemical methods. In the most cases, the enthalpy of substitution for water by organophosphorus compounds is negative. The complexes are studied in solutions using ethyl (diethoxyphosphoryl) acetate as a model compound. The mixed-ligand lanthanide complexes with acylpyrazolones and ethyl (diethoxyphosphoryl) acetate are synthesized. The crystal structure is determined for the samarium complex.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    Yu. A. Belousov, A. A. Drozdov, P. P. Verteletskii, A. A. Prishchenko, L. I. Livantsova & O. P. Novikova

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  1. Yu. A. Belousov
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  2. A. A. Drozdov
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  3. P. P. Verteletskii
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  4. A. A. Prishchenko
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  5. L. I. Livantsova
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  6. O. P. Novikova
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Corresponding author

Correspondence to Yu. A. Belousov.

Additional information

Original Russian Text © Yu.A. Belousov, A.A. Drozdov, P.P. Verteletskii, A.A. Prishchenko, L.I. Livantsova, O.P. Novikova, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 3, pp. 181–186.

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Belousov, Y.A., Drozdov, A.A., Verteletskii, P.P. et al. Mixed-ligand lanthanide complexes with acylpyrazolones and phosphorus-containing ligands. Russ J Coord Chem 39, 278–282 (2013). https://doi.org/10.1134/S1070328413030020

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  • DOI: https://doi.org/10.1134/S1070328413030020

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