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Mixed-ligand complexes of alkaline-earth metal trifluoroacetates with monoethanolamine

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Abstract

The mixed-ligand complexes of the formula [M(CF3COO)2(MEA) n ] (MEA is monoethanolamine; M = Ca (I) and Sr (II), n = 1.5; M = Ba (III), (n = 1) were obtained from appropriate salts M(CF3COO)2 · nH2O and MEA in ethanol. Complexes I–III were characterized by elemental analysis data and IR spectra. Slow crystallization of a solution of complex III in air gave a single crystal of the formula [Ba(CF3COO)2(MEA)(H2O)], which is a coordination polymer with C.N.(Ba) 9 (X-ray diffraction data). Thermal analysis showed that complexes I–III decompose under argon and in air to the corresponding fluorides at T < 400°C.

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Authors and Affiliations

  1. Moscow State University, Moscow, Russia

    A. V. Kharchenko, A. M. Makarevich & N. P. Kuzmina

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. A. Lysenko

Authors
  1. A. V. Kharchenko
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  2. A. M. Makarevich
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  3. K. A. Lysenko
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  4. N. P. Kuzmina
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Correspondence to A. V. Kharchenko.

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Original Russian Text © A.V. Kharchenko, A.M. Makarevich, K.A. Lysenko, N.P. Kuzmina, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 11, pp. 814–820.

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Kharchenko, A.V., Makarevich, A.M., Lysenko, K.A. et al. Mixed-ligand complexes of alkaline-earth metal trifluoroacetates with monoethanolamine. Russ J Coord Chem 36, 804–809 (2010). https://doi.org/10.1134/S1070328410110047

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  • DOI: https://doi.org/10.1134/S1070328410110047

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