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Synthesis and X-ray diffraction study of uranyl malonate monohydrate

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Radiochemistry Aims and scope

Abstract

Uranyl malonate monohydrate [UO2(mal)(H2O)], where mal2– is malonate ion, was synthesized and studied by single crystal X-ray diffraction. The main structural units are electrically neutral [UO2(mal)(H2O)] layers belonging to crystal-chemical group AQ21М1 (A = UO 2+2 , Q21 = mal2–, M1 = H2O) of uranyl complexes. Specific features of the packing of the uranium-containing complexes are discussed on the basis of Voronoi–Dirichlet tessellation. The structural differences between the monohydrate synthesized and the known uranyl malonate trihydrate are considered.

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Authors and Affiliations

  1. Samara National Research University, ul. Akad. Pavlova 1, Samara, 443011, Russia

    Ya. A. Medvedkov, L. B. Serezhkina, E. F. Rogalev, D. V. Pushkin & V. N. Serezhkin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow, 119071, Russia

    M. S. Grigor’ev

Authors
  1. Ya. A. Medvedkov
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  2. M. S. Grigor’ev
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  3. L. B. Serezhkina
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  4. E. F. Rogalev
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  5. D. V. Pushkin
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  6. V. N. Serezhkin
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Corresponding author

Correspondence to L. B. Serezhkina.

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Original Russian Text © Ya.A. Medvedkov, M.S. Grigor’ev, L.B. Serezhkina, E.F. Rogaleva, D.V. Pushkin, V.N. Serezhkin, 2017, published in Radiokhimiya, 2017, Vol. 59, No. 2, pp. 101–105.

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Medvedkov, Y.A., Grigor’ev, M.S., Serezhkina, L.B. et al. Synthesis and X-ray diffraction study of uranyl malonate monohydrate. Radiochemistry 59, 113–118 (2017). https://doi.org/10.1134/S1066362217020023

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  • DOI: https://doi.org/10.1134/S1066362217020023

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