Skip to main content
Log in

Distribution of rare-earth (Y, La, Ce) and other heavy metals in the profiles of the podzolic soil group

  • Soil Chemistry
  • Published:
Eurasian Soil Science Aims and scope Submit manuscript

Abstract

Along with Fe and Al, many heavy metals (Mn, Cr, Zn, Cu, and Ni) show a markedly pronounced eluvial-illuvial redistribution in the profiles of soils of the podzolic group. The intensity of the redistribution of the bulk forms of these metals is comparable with that of Fe and exceeds that of Al. Although the podzolic soils are depleted of rare-earth metals, the latter respond readily to soil podzolization. The inactive participation of Al is explained by an insignificant portion of the active reaction-capable fraction. Podzolization does not influence the profile distribution of Sr and Ba. The leaching degree of heavy metals such as Mn, Cr, Zn, Ni, and Zr is noticeably higher in the sandy podzols than in the loamy podzolic soils. Leaching of heavy metals from the podzolic horizons is of geochemical importance, whereas the depletion of metals participating in plant nutrition and biota development is of ecological importance. The leaching of heavy metals is related to the destruction of clay particles in the heavy-textured podzolic soils; the effect of the soil acidity on the leaching of heavy metals is less significant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yu. N. Vodyanitskii, Chemistry and Mineralogy of Soil Iron (Pochv. Inst. im. V.V. Dokuchaeva, Moscow, 2003) [in Russian].

    Google Scholar 

  2. Yu. N. Vodyanitskii, A. A. Vasil’ev, A. T. Savichev, and A. N. Chashchin, “The Influence of Technogenic and Natural Factors on the Content of Heavy Metals in Soils of the Middle CisUrals Region: The Town of Chusovoi and Its Suburbs,” Pochvovedenie, No. 9, 1089–1099 (2010) [Eur. Soil Sci. 43 (9), 1011–1023 (2010)].

  3. V. V. Dobrovol’skii, Supergenesis of the Quaternary Period (Nedra, Moscow, 1966) [in Russian].

    Google Scholar 

  4. V. V. Dobrovol’skii, Fundamentals of Biogeochemistry (ACADEMIA, Moscow, 2003) [in Russian].

    Google Scholar 

  5. V. V. Ivanov, Ecological Geochemistry of Elements (Ekologiya, Moscow, 1996) [in Russian].

    Google Scholar 

  6. V. V. Ivanov, Ecological Geochemistry of Elements (Ekologiya, Moscow, 1997) [in Russian].

    Google Scholar 

  7. A. Kabata-Pendias and H. Pendias, Trace Elements in Soils and Plants, (CRC, Boca Raton, 1985; Mir, Moscow, 1989).

    Google Scholar 

  8. I. S. Kaurichev and D. S. Orlov, Oxidation-Reduction Processes and Their Role in the Genesis and Fertility of Soils (Kolos, Moscow, 1982) [in Russian].

    Google Scholar 

  9. Yu. Yu. Lur’e, Handbook on Analytical Chemistry (Khimiya, Moscow, 1979) [in Russian].

    Google Scholar 

  10. L. V. Perelomov, “Interaction of Rare-Earth Elements with Biotic and Abiotic Components of Soils,” Agrokhimiya, No. 11, 85–96 (2007).

  11. A. I. Perel’man, Geochemistry of Landscape (Vysshaya shkola, Moscow, 1975) [in Russian].

    Google Scholar 

  12. Soil Science, Ed. by I. S. Kaurichev (Agropromizdat, Moscow, 1989) [in Russian].

    Google Scholar 

  13. N. A. Protasova and A. P. Shcherbakov, Microelements (Sr, V, Ni, Mn, Zn, Su, Co, Ti, Zr, Ga, Ve, Va, Sr, V, I, Mo) in Chernozems and Gray Forest Soils of the Central Chernozemic Region (Izd. Voronezhsk. Gos. Univ., Voronezh, 2003) [in Russian].

    Google Scholar 

  14. H. J. M. Bowen, Environmental Chemistry of Elements (Academic, New York, 1979).

    Google Scholar 

  15. H. J. M. Bowen, Trace Elements in Biochemistry (Academic, London-N.Y., 1966).

    Google Scholar 

  16. J. J. Braun, J. Viers, B. Dupre, et al., “Solid/Liquid REE Fractionation in the Lateritic System of Goyoum, East Cameroon: The Implication for the Present Dynamics of Soil Covers of the Humid Tropical Regions,” Ceochim. Cosmochim. Acta 62, 273–299 (2005).

    Article  Google Scholar 

  17. X. D. Cao, Y. Chen, X. R. Wang, and X. H. Deng, “Effects of Redox Potential and pH Value on the Release of Rare Elements from Soil,” Chemosphere 44, 655–661 (2001).

    Article  Google Scholar 

  18. M. Land, B. Ohlander, J. Ingri, and J. Thunberg, “Solid Speciation and Fractionation of Rare Elements in a Spodosol Profile from Northern Sweden as Revealed by Sequential Extraction,” Chem. Geol. 160, 121–138 (1999).

    Article  Google Scholar 

  19. A. Manceau, M. C. Boisset, G. Sarret, J. L. Hazemann, et al., “Direct Determination of Lead Speciation in Contaminated Soils by EXAFS Spectroscopy,” Environ. Sci. Technol. 30, 1540–1552 (1996).

    Article  Google Scholar 

  20. A. Manceau, M. A. Marcus, and N. Tamura, “Quantitative Speciation of Heavy Metals in Soils and Sediments by Synchrotron X-Ray Techniques,” in Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Science (Reviews in Mineralogy and Geochemistry, Vol. 49) (Washington DC, 2002), pp. 341–428.

  21. L. Minarik, A. Zigova, J. Bendl, P. Skrivan, and M. Stastny, “The Behavior of Rare Elements and Y during the Rock Weathering and Soil Formation in the Ricany Granite Massif, Central Bohemia,” Sci. Total Environ. 211, 101–111 (1998).

    Article  Google Scholar 

  22. A. T. Savichev and Yu. N. Vodyanitskii, “Determination of Barium, Lanthanum and Cerium Contents in Soil by X-ray Radiometric Method,” Eur. Soil Sci. 42(13), 1361–1469 (2009).

    Google Scholar 

  23. Soils and Perennial Underground Ice of Glaciated and Karst Landscapes in Northern European Russia, Ed. by S. V. Goryachkin and E.-M. Pfeifer (Inst. Geogr., Moscow, 2005).

    Google Scholar 

  24. G. Tyler, “Rare Earth Elements in Soil and Plant Systems — A Review,” Plant Soil 267, 191–206 (2004).

    Article  Google Scholar 

  25. G. Tyler, “Vertical Distribution of Mayor, Minor, and Rare Elements in Haplic Podzol,” Geoderma 119, 277–290 (2004).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © Yu.N. Vodyanitskii, S.V. Goryachkin, A.T. Savichev, 2011, published in Pochvovedenie, 2011, No. 5, pp. 546–555.

Hereinafter, the podzolic group of soils includes Al-Fe-humus podzols on sands, texturally differentiated podzolic soils on bilayered deposits, and soddy-podzolic soils on loams.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vodyanitskii, Y.N., Goryachkin, S.V. & Savichev, A.T. Distribution of rare-earth (Y, La, Ce) and other heavy metals in the profiles of the podzolic soil group. Eurasian Soil Sc. 44, 500–509 (2011). https://doi.org/10.1134/S1064229311030173

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1064229311030173

Keywords

Navigation