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New Microporous Copper Diphosphate Chloride in a Series of Homeotypic Compounds: Hydrothermal Synthesis, Crystal Structure, and Crystal Chemistry

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Abstract

Single crystals of the new zeolite-like copper diphosphate chloride |(NH4)5(H2O)9CaVCl3(OH)| [(Cu6(P2O7)4Cl3] were prepared by the hydrothermal synthesis route. The crystal structure of the new compound was studied by X-ray diffraction using synchrotron radiation (λ = 0.64066 Å) at T = 100 К (R = 0.052): a = 17.9357(5) Å, c = 13.5377(4) Å, sp. gr. I4/mcm, Z = 4, ρcalc = 2.541 g/cm3. A copper tetramer is the main structural unit, which is formed by four CuO4Cl pyramids sharing a vertex occupied by a Cl atom. The clusters of the composition Cu4O12Cl are connected through diphosphate groups and additional Cu-centered polyhedra to form a mixed-type open framework. Large channels in the framework are occupied by \({\text{NH}}_{4}^{ + }\), V 4+, and Ca2+ cations, (OH)– and Cl– anions, and H2O molecules. Similar complex ionic inclusions are characteristic of a series of homeotypic copper diphosphate chlorides exhibiting ion-exchange properties.

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ACKNOWLEDGMENTS

We thank V.O. Yapaskurt for studying the chemical composition of the crystals by electron-probe X-ray microanalysis.

Funding

This study was financially supported by the Grant of the President of the Russian Federation for the state support of young Russian scientists–candidates of science (grant MK-1613.2021.1.5).

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Authors and Affiliations

  1. Lomonosov Moscow State University, 119991, Moscow, Russia

    G. V. Kiriukhina, O. V. Yakubovich, O. V. Dimitrova & A. S. Volkov

  2. Institute of Experimental Mineralogy, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    G. V. Kiriukhina

Authors
  1. G. V. Kiriukhina
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  2. O. V. Yakubovich
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  3. O. V. Dimitrova
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  4. A. S. Volkov
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Correspondence to G. V. Kiriukhina.

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Translated by T. Safonova

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Kiriukhina, G.V., Yakubovich, O.V., Dimitrova, O.V. et al. New Microporous Copper Diphosphate Chloride in a Series of Homeotypic Compounds: Hydrothermal Synthesis, Crystal Structure, and Crystal Chemistry. Crystallogr. Rep. 67, 545–555 (2022). https://doi.org/10.1134/S1063774522040113

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