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Synthesis and Structural Characterization of a Cobalt Coordination Polymer Assembled by Bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone and Phthalate

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Abstract

A cobalt coordination polymer with the formula of {[Co(L1)(pa)]}n (1) (L1 = bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone, H2pa = phthalic acid) was synthesized under solvothermal condition. It was characterized by infrared spectroscopy, elemental and single-crystal X-ray diffraction analyses. Crystal 1 is monoclinic, the space group is P21/c with the unit cell parameters a = 8.1394(2), b = 25.7199(5), c = 15.1719(4) Å, β = 117.554(2)°, Z = 4; R1 = 0.0405 and wR2 = 0.0953 (I > 2σ). In 1, [Co2(pa)2] bridged by pa2– anions are linked by four adjacent L1 ligands and form 2D layers.

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Funding

This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), Applied Research Projects of Yuncheng University (CY-2018019) and Scientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, China

    S.-W. Sun, G.-F. Wang & T.-T. Lu

Authors
  1. S.-W. Sun
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  2. G.-F. Wang
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  3. T.-T. Lu
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Correspondence to G.-F. Wang or T.-T. Lu.

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Sun, SW., Wang, GF. & Lu, TT. Synthesis and Structural Characterization of a Cobalt Coordination Polymer Assembled by Bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone and Phthalate. Crystallogr. Rep. 65, 1142–1144 (2020). https://doi.org/10.1134/S1063774520070238

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  • DOI: https://doi.org/10.1134/S1063774520070238

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