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Synthesis of a Cobalt Coordination Polymer Based on 4-(1H-Imidazol-1-yl)phenyl)methanone and Fumaric Acid

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Abstract

A cobalt coordination polymer with V-shaped ligands, {[Co0.5(L1) ⋅ (C4H2O4)0.5] ⋅ 0.25H2O}n, (L1 = 4-(1H-imidazol-1-yl)phenyl)methanone, C4H2O4 = fumarate) has been synthesized under the solvothermal conditions. It has been characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction analysis. The crystal is crystallized in the monoclinic space group C2/m with the unit cell parameters a = 10.6921(6) Å, b = 20.7735(10) Å, c = 8.8688(5) Å, and β = 107.615(6)°, Z = 4. X-ray crystal analysis reveals that the 1D [Co(L1)4] chains are linked by two adjacent fumarate ligands to form a 2D framework.

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REFERENCES

  1. P. Huang, C. Chen, F. Jiang, et al., Cryst. Growth Des. 19, 3103 (2019).

    Article  Google Scholar 

  2. C. Zhuo, F. Wang, J. Zhang, et al., Cryst. Growth Des. 19, 3120 (2019).

    Article  Google Scholar 

  3. Y. Ye, H. Zhang, L. Chen, et al., Inorg. Chem. 58, 7754 (2019).

    Article  Google Scholar 

  4. M. Kumar, L.-H. Wu, M. Kariem, et al., Inorg. Chem. 58, 7760 (2019).

    Article  Google Scholar 

  5. F. Luo, Y. X. Che, and J. M. Zheng, Cryst. Growth Des. 9, 1066 (2008).

    Article  Google Scholar 

  6. G. E. Gomez, J. A. Ridenour, N. M. Byrne, et al., Inorg. Chem. 58, 7243 (2019).

    Article  Google Scholar 

  7. S.-H. Zhang, N. Li, C. M. Ge, et al., Dalton Trans. 40, 3000 (2011).

    Article  Google Scholar 

  8. W.-G. Lu, D.-C. Zhong, L. Jiang, et al., Cryst. Growth Des. 12, 3675 (2012).

    Article  Google Scholar 

  9. L. Yang, S.-H. Zhang, W. Wang, et al., Polyhedron 74, 49 (2014).

    Article  Google Scholar 

  10. G.-F. Wang, X. Zhang, S.-W. Sun, et al., Z. Naturforsch. 71b, 869 (2016).

    Article  Google Scholar 

  11. G.-F. Wang, X. Zhang, Z.-R. Liu, et al., Z. Naturforsch. 72b, 83 (2017).

    Article  Google Scholar 

  12. G.-F. Wang, X. Zhang, S.-W. Sun, et al., Z. Naturforsch. 72b, 257 (2017).

    Article  Google Scholar 

  13. G.-F. Wang, S.-W. Sun, W.-B. Wang, et al., Z. Naturforsch. 74b, 261 (2019).

    Article  Google Scholar 

  14. X. Yang, G.-F. Wang, and L. Yang, J. Struct. Chem. 59, 1684 (2018).

    Article  Google Scholar 

  15. Agilent Technologies, XCalibur, C. C. D. System, CrysAlisPro, Version 1.171. 35.19 (Agilent Technologies Inc., Santa Clara, CA, 2011).

    Google Scholar 

  16. G. M. Sheldrick, Program for Multi-Scan Absorption Correction (Univ. of Göttingen, Göttingen, 2000).

    Google Scholar 

  17. P. T. Beurskens, G. Admiraal, and G. Beurskens, The DIRDIF Program System, Technical Report of the Crystallography Laboratory (Univ. of Nijmegen, Nijmegen, 1992).

    Google Scholar 

  18. G. M. Sheldrick, Program for Crystal Structure Solution and Refinement (Univ. of Göttingen, Göttingen, 2000).

    Google Scholar 

  19. L.-S. Cui, X.-M. Meng, Y.-G. Li, et al., CrystEngComm 21, 3798 (2019)

    Article  Google Scholar 

  20. D. Cheng, M. A. Khan, and R. P. Houser, Inorg. Chim. Acta 351, 242 (2003).

    Article  Google Scholar 

  21. W. Wang, R. Wang, L. Liu, et al., Cryst. Growth Des. 18, 3449 (2018).

    Article  Google Scholar 

  22. J. Hao, Y. Zhao, B. Yu, et al., Transition Met. Chem. 39, 741 (2014).

    Google Scholar 

  23. Y. Wang, Y. Qi, Q. Li, et al., Polyhedron 85, 389 (2015).

    Article  Google Scholar 

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Funding

This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), Applied Research Projects of Yuncheng University (CY-2018019), and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, China

    S-W. Sun, G.-F. Wang, J. Song & B.-W. Chang

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  1. S-W. Sun
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  2. G.-F. Wang
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  3. J. Song
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  4. B.-W. Chang
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Correspondence to G.-F. Wang.

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Sun, SW., Wang, GF., Song, J. et al. Synthesis of a Cobalt Coordination Polymer Based on 4-(1H-Imidazol-1-yl)phenyl)methanone and Fumaric Acid. Crystallogr. Rep. 65, 1138–1141 (2020). https://doi.org/10.1134/S1063774520070226

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  • DOI: https://doi.org/10.1134/S1063774520070226

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