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Structural features of compounds of the sillenite family

  • Structure of Inorganic Compounds
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Abstract

It is shown that the real composition and structure of phases belonging to the sillenite family can be determined using a complex of techniques (diffraction methods, vibrational and X-ray absorption spectroscopy, and electron probe X-ray microanalysis) with a subsequent crystal-chemical analysis of the data. Refined compositions are presented for phases of nominal composition Bi24 M 2O40 with M = Zn2+, Al3+, Ga3+, Fe3+, Si4+, Ti4+, Mn4+, and P5+, which demonstrate types and concentrations of point defects as functions of the M type.

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Authors and Affiliations

  1. Lomonosov State University of Fine Chemical Technology, Moscow, 119571, Russia

    T. I. Mel’nikova & G. M. Kuz’micheva

  2. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    N. B. Bolotina

  3. Moscow State University, Moscow, Russia

    V. B. Rybakov

  4. National Research Centre “Kurchatov Institute”, pl. Akademika Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

  5. State Scientific Center of the Russian Federation, Karpov Institute of Physical Chemistry, Moscow, 105064, Russia

    N. V. Sadovskaya

  6. Institute of Experimental Mineralogy, Russian Academy of Sciences, ul. Institutskaya 4, Chernogolovka, Moscow oblast, 142432, Russia

    E. A. Mar’ina

Authors
  1. T. I. Mel’nikova
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  2. G. M. Kuz’micheva
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  3. N. B. Bolotina
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  4. V. B. Rybakov
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  5. Ya. V. Zubavichus
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  6. N. V. Sadovskaya
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  7. E. A. Mar’ina
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Corresponding author

Correspondence to G. M. Kuz’micheva.

Additional information

Original Russian Text © T.I. Mel’nikova, G.M. Kuz’micheva, N.B. Bolotina, V.B. Rybakov, Ya.V. Zubavichus, N.V. Sadovskaya, E.A. Mar’ina, 2014, published in Kristallografiya, 2014, Vol. 59, No. 3, pp. 396–404.

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Mel’nikova, T.I., Kuz’micheva, G.M., Bolotina, N.B. et al. Structural features of compounds of the sillenite family. Crystallogr. Rep. 59, 353–361 (2014). https://doi.org/10.1134/S1063774514030134

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  • DOI: https://doi.org/10.1134/S1063774514030134

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