Skip to main content
Log in

Polylysine Adsorption on Fused Quartz Surface

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

The kinetics of adsorption of two polylysine samples with different molecular weights from aqueous solutions on the surface of fused quartz has been studied by the capillary electrokinetics method. It has been found that the adsorption of positively charged polylysine on the negatively charged quartz surface decreases the absolute value of the initial ζ potential; moreover, in the case of polylysine with the higher molecular weight, it leads to the reversal of the surface charge. The constant values of the ζ potential and the times for which these values are reached depend on the molecular weight and concentration of polylysine. The rate of variations in the ζ potential is highest during the first several minutes of the solution contact with the surface. A decrease in the electric conductivity during polylysine adsorption has, for the first time, been observed, thus leading to a hypothesis that large aggregates are formed on the quartz surface. The measurement of the deformability of the layers has shown that, under our experimental conditions, dense undeformable layers are formed. Polylysines are irreversibly adsorbed on the quartz surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Picart, C., Lavalle, Ph., Hubert, P., Cuisinier, F.J.G., Decher, G., Schaaf, P., and Voegel, J.-C., Langmuir, 2001, vol. 17, p. 7414.

    Article  CAS  Google Scholar 

  2. Barrantes, A., Wengenroth, J., Arnebrant, Th., and Haugen, H.J., J. Colloid Interface Sci., 2017, vol. 485, p. 288.

    Article  CAS  Google Scholar 

  3. Zhen, G., Eggli, V., Voros, J., Zamaretti, P., Textor, M., Glokshuber, R., and Kuenneman, E., Langmuir, 2004, vol. 20, p. 10464.

    Article  CAS  Google Scholar 

  4. Huang, N.-P., Michel, R., Voros, J., Textor, M., Hofer, R., Rossi, A., Elbert, D.L., Hubbet, J.A., and Spencer, N.D., Langmuir, 2001, vol. 17, p. 489.

    Article  CAS  Google Scholar 

  5. Lee, S. and Spencer, N.D., Langmuir, 2008, vol. 24, p. 9479.

    Article  CAS  Google Scholar 

  6. Borden, M.A., Caskey, Ch.F., Little, E., Gilliers, R.J., and Ferrara, K.W., Langmuir, 2007, vol. 23, p. 9401.

    Article  CAS  Google Scholar 

  7. Kim, S.H., Jeong, J.H., Chan, K.K., and Park, T.G., Langmuir, 2005, vol. 21, p. 8852.

    Article  CAS  Google Scholar 

  8. Jardan, C.E., Frey, B.L., Kornguth, S., and Corn, R.M., Langmuir, 1994, vol. 10, p. 3642.

    Article  Google Scholar 

  9. Choi, J.-H., Kim, S.-Oh., Linardy, E., Dreaden, E.C., Zdanov, V.P., Hammond, P.T., and Cho, N.-J., J. Phys. Chem. B, 2015, vol. 119, p. 10554.

    Article  CAS  Google Scholar 

  10. Jiang, M., Popa, L., Maroni, P., and Borkovec, M., Colloids Surf. A, 2010, vol. 360, p. 20.

    Article  CAS  Google Scholar 

  11. Wu, J., Liu, B., Zhang, H., and Song, B., Meas. Sci. Technol., 2017, vol. 28, p. 115103.

    Article  Google Scholar 

  12. Morga, M., Adamczyk, Z., Godrich, S., Ocwieja, M., and Papastavrou, G., J. Colloid Interface Sci., 2015, vol. 456, p. 116.

    Article  CAS  Google Scholar 

  13. Morga, M., Adamczyk, Z., Kosior, D., and Kujda-Kruk, M., Langmuir, 2019, vol. 35, p. 12042.

    Article  CAS  Google Scholar 

  14. Marukovich, N.I., Nesterenko, A.M., and Ermakov, Yu.A., Biol. Membr., 2014, vol. 31, p. 401.

    CAS  Google Scholar 

  15. Molotkovsky, R.Yu., Galimzyanov, T.R., and Ermakov, Yu.A., Colloid J., 2019, vol. 81, p. 125.

    Article  CAS  Google Scholar 

  16. Kostriskii, A.Yu., Kondinskaia, D.A., Nesteren-ko, A.M., and Gurtovenko, A.A., Langmuir, 2016, vol. 33, p. 10402.

    Article  Google Scholar 

  17. Finogeeva, O.A., Batishchev, O.V., Ingenbom, A.V., Zolotarevskii, V.I., and Ermakov, Yu.A., Biol. Membr., 2009, vol. 26, p. 429.

    Google Scholar 

  18. Richert, L., Arntz, Y., Shaaf, P., Voegel, J.-C., and Picart, C., Surf. Sci., 2004, vol. 570, p. 13.

    Article  CAS  Google Scholar 

  19. Ren, K., Ji, J., and Shen, J., Biomaterials, 2006, vol. 27, p. 1152.

    Article  CAS  Google Scholar 

  20. Churaev, N.V., Sergeeva, I.P., Sobolev, V.D., and Derjaguin, B.V., J. Colloid Interface Sci., 1981, vol. 84, p. 451.

    Article  CAS  Google Scholar 

  21. Messina, R., Holm, C., and Kremer, K., Langmuir, 2003, vol. 19, p. 4473.

    Article  CAS  Google Scholar 

  22. Messina, R., J. Chem. Phys., 2003, vol. 119, p. 8133.

    Article  CAS  Google Scholar 

  23. Shafir, A. and Andellman, D., Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top., 2004, vol. 70, p. 061804.

    Article  Google Scholar 

  24. Ermakova, T.B., Sergeeva, I.P., Anuchkina, A.D., Sobolev, V.D., and Churaev, N.V., Prog. Colloid Polym. Sci., 2006, vol. 132, p. 95.

    Article  CAS  Google Scholar 

  25. Sergeeva, I.P., Ermakov, T.B., Semenov, D.A., Sobolev, V.D., Kiseleva, O.A., and Churaev, N.V., Colloid J., 2008, vol. 70, p. 604.

    Article  Google Scholar 

  26. Sergeeva, I.P., Semenov, D.A., Sobolev, V.D., and Churaev, N.V., Colloid J., 2008, vol. 70, p. 616.

    Article  CAS  Google Scholar 

Download references

Funding

This work was performed within the framework of the state order to the Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. D. Sobolev.

Ethics declarations

The authors declare that they have no conflict of int-erest.

Additional information

Translated by L. Tkachenko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sergeeva, I.P., Sobolev, V.D. Polylysine Adsorption on Fused Quartz Surface. Colloid J 82, 592–596 (2020). https://doi.org/10.1134/S1061933X20040110

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X20040110

Navigation