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Effect of lower alcohols on adsorption characteristics of sodium dodecyl sulfate solutions at liquid-gas interfaces

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Abstract

The dynamics of a decrease in the surface tension is studied for aqueous solutions of sodium dodecyl sulfate and its mixtures with lower alcohols (ethanol and n-propanol). Two approaches are analyzed as applied to the estimation of the adsorption of two surfactants from their mixed solutions at a liquid—gas interface, i.e., the Frumkin generalized model and the Fainerman—Miller model. It is shown that both approaches adequately describe the concentration dependences experimentally measured for the surface tension of sodium dodecyl sulfate—lower alcohol mixtures.

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Authors and Affiliations

  1. Institute of Physicoorganic and Coal Chemistry, National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, Donetsk, 83114, Ukraine

    A. I. Kovtun, S. L. Khil’ko & V. I. Rybachenko

  2. Donetsk National University of Medicine, pr. Il’icha 16, Donetsk, 83003, Ukraine

    S. A. Zholob

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  1. A. I. Kovtun
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  2. S. L. Khil’ko
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  3. S. A. Zholob
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  4. V. I. Rybachenko
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Original Russian Text ©A.I. Kovtun, S.L. Khil’ko, S.A. Zholob, V.I. Rybachenko, 2010, published in Kolloidnyi Zhurnal, 2010, Vol. 72, No. 3, pp. 380–386.

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Kovtun, A.I., Khil’ko, S.L., Zholob, S.A. et al. Effect of lower alcohols on adsorption characteristics of sodium dodecyl sulfate solutions at liquid-gas interfaces. Colloid J 72, 389–395 (2010). https://doi.org/10.1134/S1061933X10030129

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  • DOI: https://doi.org/10.1134/S1061933X10030129

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