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X-ray electron probe microanalysis of the reaction zone of thermally stimulated heterovalent anion substitution in the Ga III2 Se VI3 -GaAs solid-phase system

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Abstract

X-ray electron probe microanalysis (EPMA) was used to study the concentration profiles of the main reaction components in the Ga2Se3-GaAs heterojunction obtained as a result of thermally stimulated heterovalent anion substitution. It has been found that the quasi-equilibrium and quasi-steady diffusion modes for delivery of chalcogen to the reaction zone are different with respect to the kinetics of the A III2 C VI3 layer growth. Independent of this, the concentration profiles of the reaction elements are self-organized with time, which allows heterostuctures with a sharp interphase boundary to be reproduced.

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References

  1. V. F. Antyushin, A. V. Budanov, D. S. Kukharenko, et al., Semiconductors 37, 1311 (2003).

    Article  CAS  Google Scholar 

  2. B. L. Agapov, V. F. Antyushin, A. V. Budanov, et al., Poverkhnost’, no. 1, 70 (2006).

  3. V. N. Bessolov and M. V. Lebedev, Semiconductors 32, 1141 (1998).

    Article  Google Scholar 

  4. B. I. Sysoev, V. F. Antyushin, V. D. Strygin, et al., Tech. Phys. 31, 544 (1986).

    Google Scholar 

  5. B. I. Sysoev, A. V. Budanov, and V. D. Strygin, in Semi-conductors and Heterojunctions (Valgus, Tallinn, 1987) [in Russian].

    Google Scholar 

  6. V. S. Postnikov, B. I. Sysoev, A. V. Budanov, et al., Phys. Status Solidi A 109, 463 (1988).

    Article  CAS  Google Scholar 

  7. B. I. Sysoev, N. N. Bezryadin, A. V. Budanov, et al., Mikroelektronika 19, 591 (1990).

    CAS  Google Scholar 

  8. B. I. Sysoev, N. N. Bezryadin, A. V. Budanov, et al., Phys. Status Solidi A 124, 177 (1991).

    Article  CAS  Google Scholar 

  9. N. N. Bezryadin, A. V. Budanov, E. A. Tatokhin, et al., Inorg. Mater. 36, 864 (2000).

    Article  CAS  Google Scholar 

  10. B. L. Agapov, N. N. Bezryadin, Yu. V. Synorov, et al., J. Surf. Invest. 1, 750 (2007).

    Article  Google Scholar 

  11. E. A. Dolgopolova, A. M. Samoilov, and Yu. V. Synorov, Poverkhnost’, no. 10, 17 (2008).

  12. B. L. Agapov, A. V. Budanov, and A. Yu. Semikin, in Proceedings of the 21st Russian Conference on Electron Microscopy EM 2006 (Chernogolovka, 2006), p. 149.

  13. H. Yakowitz and D. E. Newbury, in Proceedings of the 9th Annual Scanning Electron Mirosope Symposium SEM 1976 (Illinois Inst. of Technology, Chicago, 1976), p. 151.

    Google Scholar 

  14. B. F. Ormont, Introduction to the Physical Chemistry and Crystal Chemistry of Semiconductors (Vyssh. Shkola, Moscow, 1973).

    Google Scholar 

  15. V. F. Antyushin, A. V. Budanov, E. A. Tatokhin, et al., Izv. Vyssh. Uchebn. Zaved., Elektron., no. 5, 9 (2002).

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Correspondence to A. V. Budanov.

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Original Russian Text © A.V. Budanov, B.L. Agapov, Ya.A. Boldyreva, V.D. Strygin, E.A. Tatokhin, 2012, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2012, No. 1, pp. 21–27.

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Budanov, A.V., Agapov, B.L., Boldyreva, Y.A. et al. X-ray electron probe microanalysis of the reaction zone of thermally stimulated heterovalent anion substitution in the Ga III2 Se VI3 -GaAs solid-phase system. J. Surf. Investig. 6, 19–24 (2012). https://doi.org/10.1134/S1027451012010053

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  • DOI: https://doi.org/10.1134/S1027451012010053

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