Abstract
The results of our studies of solid solutions of the general composition Bi4V2 − x Fex/2Crx/2O11 − δ are presented. The crystal-chemical parameters of different polymorphic modifications of BIMEVOX were determined. The particle size distribution was determined by laser diffraction and optical microscopy. The surface of sintered preforms was studied by scanning electron microscopy. The conductivity of sintered poly-crystalline samples as a function of temperature and composition was studied by impedance spectroscopy. The conductivity was depends on the procedure for the synthesis of solid solutions. The most promising compositions were revealed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Abraham, F., Boivin, J.C., Mairesse, G., and Nowogrocki, G., Solid State Ionics, 1990, vols. 40–41, p. 934.
Abrahams, I. and Krok, F., J. Mater. Chem., 2002, vol. 12, p. 3351.
Vannier, R.N., Mairesse, G., and Abraham, F., Solid State Ionics, 1995, vol. 78, nos. 1–4, p. 183.
Emel’yanova, Yu.V., Morozova, M.V., Mikhailovskaya, Z.A., Velichko, E.V., Buyanova, E.S., and Zhukovskii, V.M., Elektrokhimiya, 2009, vol. 45, p. 407 [Russ. J. Electrochem., (Engl. Transl.), 2009, vol. 45, p. 382].
Krok, F., Abraham, I., Bangobango, D.C., Bogusz, W., and Nelstrop, J.A.G., Solid State Ionics, 1996, vols. 86–88, p. 261.
Yan, J. and Greenblatt, M., Solid State Ionics, 1995, vol. 81, p. 225.
Buyanova, E.S., Petrova, S.A., Emel’yanova, Yu.V., et al., Zh. Neorg. Khim., 2009, vol. 54, no. 6, p. 928 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 54, no. 6, p. 864].
Emel’yanova, Yu.V., Buyanova, E.S., and Zhukovskii, V.M., Elektrokhimiya, 2005, vol. 41, p. 607. [Russ. J. Electrochem. (Engl. Transl.), 2005, vol. 41, p. 532].
Buyanova, E.S., Petrova, S.A., Emel’yanova, Yu.V., et al., Zh. Neorg. Khim., 2009, vol. 54, no. 8, p. 1257 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 54, no. 8, p. 1193].
Joubert, O., Ganne, M., Vannier, R.N., and Mairesse, G., Solid State Ionics, 1996, vol. 83, nos. 3–4, p. 199.
Lasure, S., Vernochet, C., Vannier, R.N., Nowogrocki, G., and Mairesse, G., Solid State Ionics, 1996, vol. 90, p. 117.
Taninouchi, Y., Uda, T., Ichitsubo, T., Awakura, Y., and Matsubara, E., Solid State Ionics, 2010, vol. 181, p. 1279.
Yaremchenko, A.A., Kharton, V.V., Naumovich, E.N., and Marques, F.M.B., J. Electroceramics, 2000, vol. 4, no. 1, p. 233.
Guillodo, M., Fouletier, J., Dassemond, L., and Del Gallo, P., J. Europe. Ceram. Soc., 2001, vol. 21, p. 2331.
Diffract Plus: Topas Bruker AXS GmbH, Ostliche. Rheinbruckenstrabe 50, D-7187, Karlsruhe: Germany, 2006.
Laugier, J. and Bochu, B., LMGP-Suite of Programs for the Interpretation of X-Ray Experiments, ENSP, Grenoble: Lab. Materiaux Genie Phys., 2003.
Politova, E.D., Fortal’nova, E.A., Kaleva, G.M., et al., Fiz. Tverd. Tela, 2009, vol. 51, no. 7, p. 1364.
Hervoches, C.H., Steil, M.C., and Muccillo, R., Solid State Sciences, 2004, vol. 6, p. 173.
Simmner, S.P., Suarez-Sandoval, D., Mackenzie, J.D., and Dunn, B., J. Am. Ceram. Soc., 1997, vol. 80, p. 2563.
Emel’yanova, Yu.V., Salimgareeva, Zh.V., Buyanova, E.S., and Zhukovskii, V.M., Neorg. Mater., 2005, vol. 41, no. 10, p. 1254.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Velichko, Z.A. Mikhailovskaya, M.V. Morozova, E.S. Buyanova, Yu.V. Emel’yanova, S.A. Petrova, V.M. Zhukovskii, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 5, pp. 602–607.
Rights and permissions
About this article
Cite this article
Velichko, E.V., Mikhailovskaya, Z.A., Morozova, M.V. et al. Synthesis, region of existence, structural characteristics, and conductivity of BI(CR, FE)VOX solid solutions. Russ J Electrochem 47, 563–568 (2011). https://doi.org/10.1134/S1023193511050181
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193511050181