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Birefringence in solutions and films of poly[4,4'-bis(4''-N-phenoxy)diphenylsulfon]imide of 1,3 bis(3',4-dicarboxyphenoxy)benzene

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Abstract

Birefringence in solutions and films of poly[4,4'-bis(4''-N-phenoxy)diphenylsulfon]imide of 1,3-bis(3',4-dicarboxyphenoxy)benzene macromolecules is studied. The method of birefringence in the flow of polymer solutions in DMF allows one to determine the proper specific optical anisotropy of the repeating unit of chain βM = +15 × 10–27 cm3 mol/g. Spontaneous birefringence in polymer films of different thickness is studied under various incidence angles of a polarized beam. The total data analysis allows one to estimate the orientation order parameter of polymer chain fragments in the vicinity of surface S 0 =–0.01, which is typical of flexible-chain polymers.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, 199004, Russia

    G. M. Pavlov, G. F. Kolbina, A. L. Didenko & V. M. Svetlichnyi

  2. Faculty of Physics, St. Petersburg State University, St. Petersburg, 199034, Russia

    G. M. Pavlov, A. S. Gubarev & I. P. Kolomiets

Authors
  1. G. M. Pavlov
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  2. A. S. Gubarev
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  3. G. F. Kolbina
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  4. I. P. Kolomiets
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  5. A. L. Didenko
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  6. V. M. Svetlichnyi
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Correspondence to G. M. Pavlov.

Additional information

Original Russian Text © G.M. Pavlov, A.S. Gubarev, G.F. Kolbina, I.P. Kolomiets, A.L. Didenko, V.M. Svetlichnyi, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 2, pp. 150–155.

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Pavlov, G.M., Gubarev, A.S., Kolbina, G.F. et al. Birefringence in solutions and films of poly[4,4'-bis(4''-N-phenoxy)diphenylsulfon]imide of 1,3 bis(3',4-dicarboxyphenoxy)benzene. Polym. Sci. Ser. A 59, 193–197 (2017). https://doi.org/10.1134/S0965545X17020079

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  • DOI: https://doi.org/10.1134/S0965545X17020079

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