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Adsorption of amphiphilic comb-shaped macromolecules on a patterned surface

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Abstract

The molecular-dynamics method is used to study the adsorption of A-graft-B macromolecules on patterned planar surfaces consisting of regions a and b that specifically interact with chain units. Surfaces with patterns in the form of circles of different radii and a spiral stripe are discussed. Effective recognition occurs during the adsorption of an A-graft-B macromolecule on these patterned surfaces. Recognition means that, for a proper combination of the architecture of a macromolecule and the energy parameters of its interaction with the plane regions, the macromolecule can be located along the boundary of a circle with a given radius or can stay in a given location of the spiral stripe.

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Authors and Affiliations

  1. Faculty of Physics, Moscow State University, Moscow, 119991, Russia

    A. A. Glagoleva & A. R. Khokhlov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    V. V. Vasilevskaya & A. R. Khokhlov

Authors
  1. A. A. Glagoleva
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  2. V. V. Vasilevskaya
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  3. A. R. Khokhlov
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Correspondence to A. A. Glagoleva.

Additional information

Original Russian Text © A.A. Glagoleva, V.V. Vasilevskaya, A.R. Khokhlov, 2011, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2011, Vol. 53, No. 4, pp. 582–592.

This work was supported by the Russian Foundation for Basic Research (project 09-03-12263-ofi_m) and the Department of State Scientific and Technology Policy and Innovation of the Ministry of Education and Science of the Russian Federation.

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Glagoleva, A.A., Vasilevskaya, V.V. & Khokhlov, A.R. Adsorption of amphiphilic comb-shaped macromolecules on a patterned surface. Polym. Sci. Ser. A 53, 344–353 (2011). https://doi.org/10.1134/S0965545X11040031

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  • DOI: https://doi.org/10.1134/S0965545X11040031

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