Skip to main content
Log in

Comblike macromolecules

  • Journal Jubilee
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

The theoretical and experimental data on the physical properties of comblike macromolecules are surveyed. Stiffening of comblike macromolecules in solution and on the surface; spontaneous curvature of adsorbed macromolecules resulting from the jump of side chains; rod-globule transitions in adsorbed macromolecules induced by various physical factors; self-organization in the systems of amphiphilic macromolecules; and certain other effects are considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. Hadjichristidis, M. Pitsikalis, S. Pispas, and H. Iatrou, Chem. Rev. 101, 3747 (2001).

    Article  CAS  Google Scholar 

  2. K. Matyjaszewski and J. Xia, Chem. Rev. 101, 2921 (2001).

    Article  CAS  Google Scholar 

  3. N. Hadjichristidis, M. Pitsikalis, and H. Iatrou, Adv. Polym. Sci. 189, 1 (2005).

    Article  CAS  Google Scholar 

  4. M. Xenidou and N. Hadjichristidis, Macromolecules 31, 5690 (1998).

    Article  CAS  Google Scholar 

  5. D. Uhrig and J. W. Mays, Macromolecules 35, 7182 (2002).

    Article  CAS  Google Scholar 

  6. Y. Zhu, R. Weildisch, S. P. Gido, et al., Macromolecules 35, 5903 (2002).

    Article  CAS  Google Scholar 

  7. G. Velis and N. Hadjichristidis, J. Polym. Sci., Part A: Polym. Chem. 38, 1136 (2000).

    Article  CAS  Google Scholar 

  8. L. Gu, Z. Shen, S. Zhang, et al., Macromolecules 40, 4486 (2007).

    Article  CAS  Google Scholar 

  9. Y. Li, Y. Wang, and C. Pan, J. Polym. Sci., Part A: Polym. Chem. 41, 1243 (2003).

    Article  CAS  Google Scholar 

  10. U. Schubert and H. Hohmeier, Macromol. Rapid Commun. 23, 561 (2002).

    Article  CAS  Google Scholar 

  11. S. Liu and A. Sen, Macromolecules 34, 1529 (2001).

    Article  CAS  Google Scholar 

  12. J. Lu, H. Liang, A. Li, and Q. Cheng, Eur. Polym. J. 40, 397 (2004).

    Article  CAS  Google Scholar 

  13. J. Chang, P. Park, and M. Han, Macromolecules 33, 321 (2000).

    Article  CAS  Google Scholar 

  14. J. S. Wang and K. Matyjaszewski, J. Am. Chem. Soc. 117, 5614 (1995).

    Article  CAS  Google Scholar 

  15. K. L. Beers, S. G. Gaynor, K. Matyjaszewski, et al., Macromolecules 31, 9413 (1998).

    Article  CAS  Google Scholar 

  16. H. G. Börner, K. L. Beers, K. Matyjaszewski, et al., Macromolecules 34, 4375 (2001).

    Article  CAS  Google Scholar 

  17. Y. Tsukahara, K. Tsutsumi, Y. Yamashita, and S. Shimada, Macromolecules 23, 5201 (1990).

    Article  CAS  Google Scholar 

  18. K. Yamada, M. Miyazaki, K. Ohno, et al., Macromolecules 32, 290 (1999).

    Article  CAS  Google Scholar 

  19. G. Ming, W. Ting, Z. Yin-Fang, and P. Cai-Yan, Polymer 42, 6385 (2001).

    Article  Google Scholar 

  20. U. Schulze, T. Fonagy, H. Komber, et al., Macromolecules 36, 4719 (2003).

    Article  CAS  Google Scholar 

  21. K. Endo and T. Sigita, J. Polym. Sci., Part A: Polym. Chem. 42, 2904 (2004).

    Article  CAS  Google Scholar 

  22. D. Zhang and C. Ortiz, Macromolecules 37, 4271 (2004).

    Article  CAS  Google Scholar 

  23. D. Pantazis, I. Chalari, and N. Hadjichristidis, Macromolecules 36, 3783 (2003).

    Article  CAS  Google Scholar 

  24. L. Onsager, Ann. N. Y. Acad. Sci. 51, 627 (1949).

    Article  CAS  Google Scholar 

  25. A. Khokhlov and A. N. Semenov, Physica A (Amsterdam) 108, 546 (1981).

    Google Scholar 

  26. L. V. Gallacher and S. Windwer, J. Chem. Phys. 44, 1139 (1966).

    Article  CAS  Google Scholar 

  27. F. L. McCrackin and J. Mazur, Macromolecules 14, 1214 (1981).

    Article  CAS  Google Scholar 

  28. S. Ya. Magarik, G. M. Pavlov, and G. A. Fomin, Macromolecules 11, 294 (1978).

    Article  CAS  Google Scholar 

  29. P. G. De Gennes, Scaling Concepts in Polymer Physics (Cornell Univ. Press, Ithaca, 1979; Mir, Moscow, 1982).

    Google Scholar 

  30. T. M. Birshtein, O. V. Borisov, E. B. Zhulina, et al., Vysokomol. Soedin., Ser. A 29, 1169 (1987).

    CAS  Google Scholar 

  31. E. B. Zhulina, Vysokomol. Soedin., Ser. B 25, 834 (1983).

    CAS  Google Scholar 

  32. E. B. Zhulina, Vysokomol. Soedin., Ser. A 26, 794 (1984).

    CAS  Google Scholar 

  33. E. B. Zhulina and T. M. Birshtein, Vysokomol. Soedin., Ser. A 27, 511 (1985).

    CAS  Google Scholar 

  34. T. M. Birshtein and E. B. Zhulina, Macromol. Theory Simul. 6, 1169 (1997).

    Article  CAS  Google Scholar 

  35. G. H. Fredrickson, Macromolecules 26, 2825 (1993).

    Article  CAS  Google Scholar 

  36. Z.-G. Wang and S. A. Safran, J. Chem. Phys. 89, 5323 (1988).

    Article  CAS  Google Scholar 

  37. E. B. Zhulina and T. A. Vilgis, Macromolecules 28, 1008 (1995).

    Article  CAS  Google Scholar 

  38. J. E. G. Lipson, Macromolecules 24, 1327 (1991).

    Article  CAS  Google Scholar 

  39. J. E. G. Lipson, Macromolecules 26, 203 (1993).

    Article  CAS  Google Scholar 

  40. A. Gauger and T. Pakula, Macromolecules 28, 190 (1995).

    Article  CAS  Google Scholar 

  41. Y. Rouault and O. V. Borisov, Macromolecules 29, 2605 (1996).

    Article  CAS  Google Scholar 

  42. M. Wintermantel, K. Fischer, M. Gerle, et al., Angew. Chem. 107, 1606 (1995).

    Article  Google Scholar 

  43. M. Saariaho, O. Ikkala, I. Szleifer, et al., J. Chem. Phys. 107, 3267 (1997).

    Article  CAS  Google Scholar 

  44. M. Saariaho, I. Szleifer, O. Ikkala, and G. Ten Brinke, Macromol. Theory Simul. 7, 211 (1998).

    Article  CAS  Google Scholar 

  45. M. Saariaho, A. Subbotin, I. Szleifer, et al., Macromolecules 32, 4439 (1999).

    Article  CAS  Google Scholar 

  46. A. Subbotin, M. Saariaho, R. Stepanyan, et al., Macromolecules 33, 6168 (2000).

    Article  CAS  Google Scholar 

  47. N. A. Denesyuk, Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 67, 051803 (2003).

  48. M. Daoud and J. P. Cotton, J. Phys. (Paris) 47, 531 (1982).

    Google Scholar 

  49. T. M. Birstein and E. B. Zhulina, Polymer 25, 1453 (1984).

    Article  Google Scholar 

  50. K. Shiokava, K. Itoh, and N. Nemoto, J. Chem. Phys. 111, 8165 (1999).

    Article  Google Scholar 

  51. L. Feuz, F. A. M. Leermakers, M. Textor, and O. Borisov, Macromolecules 38, 8891 (2005).

    Article  CAS  Google Scholar 

  52. A. Yethiraj, J. Chem. Phys. 125, 204901 (2006).

    Google Scholar 

  53. M. Schmidt and K. Fischer, Macromol. Rapid Commun. 22, 787 (2001).

    Article  Google Scholar 

  54. S. Rathgeber, T. Pakula, A. Wilk, et al., J. Chem. Phys. 122, 124904 (2005).

  55. H.-P. Hsu, W. Paul, and K. Binder, Macromol. Theory Simul. 16, 660 (2007).

    Article  CAS  Google Scholar 

  56. P. Grassberger, Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 56, 3682 (1997).

    CAS  Google Scholar 

  57. Y. Tsukahara, K. Mizuno, A. Segawa, and Y. Yamashita, Macromolecules 22, 1546 (1989).

    Article  CAS  Google Scholar 

  58. Y. Tsukahara, K. Tsutsumi, Y. Yamashita, and S. Shimada, Macromolecules 23, 5201 (1990).

    Article  CAS  Google Scholar 

  59. Y. Tsukahara, S. Kohjiya, K. Tsutsumi, and Y. Okamoto, Macromolecules 27, 1662 (1994).

    Article  CAS  Google Scholar 

  60. M. Wintermantel, M. Schmidt, Y. Tsukahara, et al., Macromol. Rapid Commun. 15, 279 (1994).

    Article  CAS  Google Scholar 

  61. H. Yamakawa and M. Fujii, Macromolecules 7, 128 (1974).

    Article  CAS  Google Scholar 

  62. T. Yoshizaki, I. Nitta, and H. Yamakawa, Macromolecules 21, 165 (1988).

    Article  CAS  Google Scholar 

  63. H. Yamakawa and T. Yoshizaki, Macromolecules 13, 633 (1980).

    Article  CAS  Google Scholar 

  64. M. Wintermantel, M. Gerle, K. Fischer, et al., Macromolecules 29, 978 (1996).

    Article  CAS  Google Scholar 

  65. S. Rathgeber, T. Pakula, A. Wilk, et al., Polymer 47, 7318 (2006).

    Article  CAS  Google Scholar 

  66. B. Zhang, F. Gröhn, J. S. Pedersen, et al., Macromolecules 39, 8440 (2006).

    Article  CAS  Google Scholar 

  67. R. Koyama, J. Phys. Soc. Jpn. 34, 1029 (1973).

    Article  CAS  Google Scholar 

  68. O. Kratky and G. Porod, Recl. Trav. Chim. Pays-Bas 68, 1106 (1949).

    CAS  Google Scholar 

  69. H. Benout and P. Doty, J. Phys. Chem. 57, 958 (1953).

    Article  Google Scholar 

  70. K. Terao, Y. Nakamura, and T. Norisuye, Macromolecules 32, 711 (1999).

    Article  CAS  Google Scholar 

  71. K. Terao, T. Hokajo, Y. Nakamura, and T. Norisuye, Macromolecules 32, 3690 (1999).

    Article  CAS  Google Scholar 

  72. N. Nemoto, M. Nagai, A. Koike, and S. Okada, Macromolecules 28, 3854 (1995).

    Article  CAS  Google Scholar 

  73. M. Gerle, K. Fischer, S. Roos, et al., Macromolecules 32, 2629 (1999).

    Article  CAS  Google Scholar 

  74. S. S. Sheiko and M. Möller, Chem. Rev. 101, 4099 (2001).

    Article  CAS  Google Scholar 

  75. V. Percec, C.-H. Ahn, G. Ungar, et al., Nature (London) 391, 161 (1998).

    Article  CAS  Google Scholar 

  76. S. A. Prokhorova, S. S. Sheiko, M. Möller, et al., Macromol. Rapid Commun. 19, 359 (1998).

    Article  CAS  Google Scholar 

  77. S. A. Prokhorova, S. S. Sheiko, M. Möller, et al., Macromolecules 32, 2653 (1999).

    Article  CAS  Google Scholar 

  78. S. A. Prokhorova, S. S. Sheiko, A. Mourran, et al., Langmuir 17, 6862 (2000).

    Article  CAS  Google Scholar 

  79. S. S. Sheiko, S. A. Prokhorova, K. L. Beers, et al., Macromolecules 34, 8354 (2001).

    Article  CAS  Google Scholar 

  80. F. Sun, S. S. Sheiko, M. Möller, et al., J. Phys. Chem., A 108, 9682 (2004).

    Article  CAS  Google Scholar 

  81. P. G. Khalatur, A. R. Khokhlov, S. A. Prokhorova, et al., Eur. Phys. J., E 1, 99 (2000).

    Article  CAS  Google Scholar 

  82. I. I. Potemkin, A. R. Khokhlov, and P. Reineker, Eur. Phys. J., E 4, 93 (2001).

    Article  CAS  Google Scholar 

  83. I. I. Potemkin, Macromolecules 40, 1238 (2007).

    Article  CAS  Google Scholar 

  84. A. Yu. Grosberg and A. R. Khokhlov, Statistical Physics of Macromolecules (Nauka, Moscow, 1989; American Institute of Physics, Ithaca, 1994).

    Google Scholar 

  85. S. S. Sheiko, F. C. Sun, A. Randall, et al., Nature (London) 440, 191 (2006).

    Article  CAS  Google Scholar 

  86. I. I. Potemkin, Macromolecules 39, 7178 (2006).

    Article  CAS  Google Scholar 

  87. S. S. Sheiko, M. Da Silva, D. G. Shirvaniants, et al., Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 44, 544 (2003).

    CAS  Google Scholar 

  88. I. I. Potemkin, Eur. Phys. J., E 12, 207 (2003).

    Article  CAS  Google Scholar 

  89. I. I. Potemkin, A. R. Khokhlov, S. A. Prokhorova, et al., Macromolecules 37, 3918 (2004).

    Article  CAS  Google Scholar 

  90. S. Alexander, J. Phys. (Paris) 38, 983 (1977).

    CAS  Google Scholar 

  91. P. G. De Gennes, Macromolecules 13, 1069 (1980).

    Article  Google Scholar 

  92. J. De Jong, A. Subbotin, and G. Ten Brinke, Macromolecules 38, 6718 (2005).

    Article  CAS  Google Scholar 

  93. A. Subbotin, J. De Jong, and G. Ten Brinke, Eur. Phys. J., E 20, 99 (2006).

    Article  CAS  Google Scholar 

  94. T. M. Birshtein, P. A. Iakovlev, V. M. Amoskov, et al., Macromolecules 41, 478 (2008).

    Article  CAS  Google Scholar 

  95. M. O. Gallyamov, B. Tartsch, A. R. Khokhlov, et al., Macromol. Rapid Commun. 25, 1703 (2004).

    Article  CAS  Google Scholar 

  96. M. O. Gallyamov, B. Tartsch, A. R. Khokhlov, et al., Chem. Eur. J. 10, 4599 (2004).

    Article  CAS  Google Scholar 

  97. M. O. Gallyamov, B. Tartsch, P. Mela, et al., Phys. Chem. Chem. Phys. 9, 346 (2007).

    Article  CAS  Google Scholar 

  98. M. O. Gallyamov, B. Tartsch, P. Mela, et al., J. Polym. Sci., Part B: Polym. Phys. 45, 2368 (1997).

    Article  CAS  Google Scholar 

  99. O. E. Perelstein, V. A. Ivanov, Yu. S. Velichko, et al., Macromol. Rapid Commun. 28, 977 (2007).

    Article  CAS  Google Scholar 

  100. S. J. Lord, S. S. Sheiko, I. LaRue, et al., Macromolecules 37, 4235 (2004).

    Article  CAS  Google Scholar 

  101. R. Stepanyan, A. Subbotin, and G. Ten Brinke, Macromolecules 35, 5640 (2002).

    Article  CAS  Google Scholar 

  102. A. V. Subbotin and A. N. Semenov, Polymer Science, Ser. A 49, 1328 (2007) [Vysokomol. Soedin., Ser. A 49, 2139 (2007)].

    Article  Google Scholar 

  103. L. Leibler, Macromolecules 13, 1602 (1980).

    Article  CAS  Google Scholar 

  104. J. De Jong and G. Ten Brinke, Macromol. Theory Simul. 13, 318 (2004).

    Article  CAS  Google Scholar 

  105. H.-P. Hsu, W. Paul, and K. Binder, Europhys. Lett. 76, 526 (2006).

    Article  CAS  Google Scholar 

  106. L. D. Landau and E. M. Lifshitz, Statistical Physics (Nauka, Moscow, 1976; Pergamon, Oxford, 1980), Part 1.

    Google Scholar 

  107. J. L. Richard and G. Sarma, J. Phys. C: Solid State Phys. 14, L617 (1981).

    Article  Google Scholar 

  108. M. E. Fisher and V. Privman, Phys. Rev. B: Condens. Matter 32, 477 (1985).

    Google Scholar 

  109. M. Zhang and A. H. E. Müller, J. Polym. Sci., Part A: Polym. Chem. 43, 3461 (2005).

    Article  CAS  Google Scholar 

  110. K. I. Popov and I. I. Potemkin, Langmuir 23, 8252 (2007).

    Article  CAS  Google Scholar 

  111. T. Stephan, S. Muth, and M. Schmidt, Macromolecules 35, 9857 (2002).

    Article  CAS  Google Scholar 

  112. G. Cheng, A. Böker, M. Zhang, et al., Macromolecules 34, 6883 (2001).

    Article  CAS  Google Scholar 

  113. R. Djalali, S. Li, and M. Schmidt, Macromolecules 35, 4282 (2002).

    Article  CAS  Google Scholar 

  114. O. V. Borisov and E. B. Zhulina, Macromolecules 38, 2506 (2005).

    Article  CAS  Google Scholar 

  115. E. Yu. Kramarenko, O. S. Pevnaya, and A. R. Khokhlov, J. Chem. Phys. 122, 084902 (2005).

  116. O. S. Pevnaya, E. Yu. Kramarenko, and A. R. Khokhlov, Polymer Science, Ser. A 49, 1233 (2007) [Vysokomol. Soedin., Ser. A 49, 1988 (2007)].

    Article  Google Scholar 

  117. F. S. Bates and G. H. Fredrickson, Annu. Rev. Phys. Chem. 41, 525 (1990).

    Article  CAS  Google Scholar 

  118. F. S. Bates and G. H. Fredrickson, Phys. Today 52(2), 32 (1999).

    Article  CAS  Google Scholar 

  119. M. W. Matsen, J. Phys.: Condens. Matter 14(2), R21 (2002).

    Article  CAS  Google Scholar 

  120. T. M. Lodge, Macromol. Chem. Phys. 204, 265 (2003).

    Article  CAS  Google Scholar 

  121. C. Park, J. Yoon, and E. L. Thomas, Polymer 22, 6725 (2003).

    Article  CAS  Google Scholar 

  122. M. W. Matsen and M. Schick, Phys. Rev. Lett. 72, 2660 (1994).

    Article  CAS  Google Scholar 

  123. A. K. Khandpur, S. Föster, F. S. Bates, et al., Macromolecules 28, 8796 (1995).

    Article  CAS  Google Scholar 

  124. I. Ya. Erukhimovich, Vysokomol. Soedin., Ser. A 24, 1942 (1982).

    CAS  Google Scholar 

  125. H. Benoit and G. Hadziioannou, Macromolecules 21, 1449 (1988).

    Article  CAS  Google Scholar 

  126. A. Shinozaki, D. Jasnow, and A. C. Balazs, Macromolecules 27, 2496 (1994).

    Article  CAS  Google Scholar 

  127. D. P. Foster, D. Jasnow, and A. C. Balazs, Macromolecules 28, 3450 (1995).

    Article  CAS  Google Scholar 

  128. A. V. Dobrynin and I. Ya. Erukhimovich, Macromolecules 26, 276 (1993).

    Article  CAS  Google Scholar 

  129. A. Werner and G. H. Fredrickson, J. Polym. Sci., Part B: Polym. Phys. 35, 849 (1996).

    Article  Google Scholar 

  130. V. V. Palyulin and I. I. Potemkin, Polymer Science, Ser. A 49, 473 (2007) [Vysokomol. Soedin., Ser. A 49, 713 (2007)].

    Article  Google Scholar 

  131. V. V. Palyulin and I. I. Potemkin, J. Chem. Phys. 127, 124903 (2007).

    Google Scholar 

  132. R. J. Nap, C. Kok, G. Ten Brinke, and S. I. Kuchanov, Eur. Phys. J., E 4, 515 (2001).

    Article  CAS  Google Scholar 

  133. R. J. Nap and G. Ten Brinke, Macromolecules 35, 952 (2002).

    Article  CAS  Google Scholar 

  134. R. J. Nap, I. Erukhimovich, and G. Ten Brinke, Macromolecules 37, 4296 (2004).

    Article  CAS  Google Scholar 

  135. Yu. G. Smirnova, G. Ten Brinke, and I. Ya. Erukhimovich, J. Chem. Phys. 124, 054907 (2006).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. I. Potemkin.

Additional information

Original Russian Text © I.I. Potemkin, V.V. Palyulin, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 2, pp. 163–195.

This work was supported by the Russian Foundation for Basic Research (project no. 07-03-00371) and the Ministry of Education and Science of the Russian Federation (a grant from the president of the Russian Federation for Support of Young Scientists, MD-597.2008.3).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Potemkin, I.I., Palyulin, V.V. Comblike macromolecules. Polym. Sci. Ser. A 51, 123–149 (2009). https://doi.org/10.1134/S0965545X09020011

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X09020011

Keywords

Navigation