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Calculation of the critical conversion and topological parameters for hyperbranched polyisocyanurate polymers prepared via cocyclotrimerization of mono- and diisocyanates

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Abstract

A new approach to the design of hyperbranched polymers, the cocyclotrimerization of mono-and diisocyanates is proposed. The kinetic scheme for the synthesis of hyperbranched polyisocyanurates was considered and calculated in the generating-function formalism. New theoretical relationships were obtained that make it possible to predict the critical conversion and a change in the structural and molecular-mass characteristics of hyperbranched polyisocyanurates in the course of the reaction, depending on the initial ratio of monoand diisocyanates and on the relative reactivity of isocyanate groups.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    T. F. Irzhak, V. I. Irzhak, G. V. Malkov, Ya. I. Estrin & E. R. Badamshina

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  1. T. F. Irzhak
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  2. V. I. Irzhak
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  3. G. V. Malkov
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  4. Ya. I. Estrin
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  5. E. R. Badamshina
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Correspondence to T. F. Irzhak.

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Original Russian Text © T.F. Irzhak, V.I. Irzhak, G.V. Malkov, Ya.I. Estrin, E.R. Badamshina, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2008, Vol. 50, No. 1, pp. 91–102.

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Irzhak, T.F., Irzhak, V.I., Malkov, G.V. et al. Calculation of the critical conversion and topological parameters for hyperbranched polyisocyanurate polymers prepared via cocyclotrimerization of mono- and diisocyanates. Polym. Sci. Ser. A 50, 74–83 (2008). https://doi.org/10.1134/S0965545X08010124

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  • DOI: https://doi.org/10.1134/S0965545X08010124

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