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Thermodynamics of acetone sorption from vapor phase by Keplerate and toroid polyoxomolybdate nanoclusters

  • Physical Chemistry of Surface Phenomena
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Abstract

The sorption of acetone from the vapor phase by Keplerate polyoxomolybdate (POM) nanoclusters, Mo132 and Mo72Fe30, and Mo138, a POM with a toroid structure, is studied via equilibrium interval sorption (a modification of vapor sorption gravimetry). The highest sorption capacity is registered for Mo132, while the other two show performance an order of magnitude lower. The specific Gibbs energy of the interaction between the POMs and acetone is reported. Small-angle X-ray and neutron scattering analysis indicates a considerable difference between the natures of Mo132 and Mo138 surfaces.

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Authors and Affiliations

  1. Research Institute of Physics and Applied Mathematics, Ural Federal University, Yekaterinburg, 620000, Russia

    A. A. Ostroushko, L. V. Adamova, E. V. Eremina, K. V. Grzhegorzhevskii & A. N. Pirogov

  2. Delft University of Technology, 2600 AA, Delft, the Netherlands

    E. V. Velichko

  3. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    S. G. Bogdanov & A. N. Pirogov

Authors
  1. A. A. Ostroushko
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  2. L. V. Adamova
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  3. E. V. Eremina
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  4. K. V. Grzhegorzhevskii
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  5. E. V. Velichko
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  6. S. G. Bogdanov
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  7. A. N. Pirogov
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Correspondence to A. A. Ostroushko.

Additional information

Original Russian Text © A.A. Ostroushko, L.V. Adamova, E.V. Eremina, K.V. Grzhegorzhevskii, E.V. Velichko, S.G. Bogdanov, A.N. Pirogov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 7, pp. 1211–1217.

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Ostroushko, A.A., Adamova, L.V., Eremina, E.V. et al. Thermodynamics of acetone sorption from vapor phase by Keplerate and toroid polyoxomolybdate nanoclusters. Russ. J. Phys. Chem. 91, 1313–1318 (2017). https://doi.org/10.1134/S0036024417070238

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  • DOI: https://doi.org/10.1134/S0036024417070238

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