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Characteristics of the mass transfer of phosphatidylcholine during its sorption on mesoporous composites based on MCM-41

  • Physical Chemistry of Surface Phenomena
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Abstract

The kinetic parameters of sorption of phosphatidylcholine on mesoporous composites based on MCM-41 are considered. It is noted that the possibility of both the diffusion and adsorption rate limitations of the process should be taken into account in the description of the kinetics of sorption of non-polar fat-soluble physiologically active compounds (PACs) from hexane solutions onto mesoporous materials of MCM- 41 type. The adequacy of using the Boyd diffusion model and the Lagergren, Ho and McKay, and Elovich models to describe the kinetics of sorption of phosphatidylcholine on mesoporous composites based on MCM-41 is shown. The contributions from diffusion limitation (internal and external) and the rate of the chemical step of adsorption to the overall rate of the sorption process are determined. It is found that the sorption of the phospholipid is a mixed diffusion process.

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Authors and Affiliations

  1. Faculty of Chemistry, Voronezh State University, Voronezh, 394036, Russia

    L. A. Sinyaeva, S. I. Karpov, N. A. Belanova & V. F. Selemenev

  2. Chemical Technology II, Institute of Chemistry, Faculty of Mathematics and Natural Sciences, University of Oldenburg, D-26111, Oldenburg, Germany

    F. Roessner

Authors
  1. L. A. Sinyaeva
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  2. S. I. Karpov
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  3. N. A. Belanova
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  4. F. Roessner
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  5. V. F. Selemenev
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Correspondence to S. I. Karpov.

Additional information

Original Russian Text © L.A. Sinyaeva, S.I. Karpov, N.A. Belanova, F. Roessner, V.F. Selemenev, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 12, pp. 1923–1930.

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Sinyaeva, L.A., Karpov, S.I., Belanova, N.A. et al. Characteristics of the mass transfer of phosphatidylcholine during its sorption on mesoporous composites based on MCM-41. Russ. J. Phys. Chem. 89, 2278–2284 (2015). https://doi.org/10.1134/S0036024415120298

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  • DOI: https://doi.org/10.1134/S0036024415120298

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