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Effect of thermochemical treatment on the surface morphology and hydrophobicity of heterogeneous ion-exchange membranes

  • Chemical Thermodynamics and Thermochemistry
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Abstract

A comparative analysis is performed on the effect thermochemical treatment in aqueous, alkali, and acid media has on the surface morphology and hydrophobicity of swelling heterogeneous ion-exchanged membranes. A correlation between changes in surface morphology and hydrophobicity is established. It is shown that under prolonged (50 h) membrane thermal treatment above room temperature, hydrophobicity is reduced due to substantial enlargement of cavities and cracks resulting from the partial destruction of inert binder (polyethylene) and reinforcing poly-ɛ-caproamide fabric (capron).

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Authors and Affiliations

  1. Voronezh State University, Voronezh, 394006, Russia

    V. I. Vasil’eva & E. M. Akberova

  2. Kuban State University, Krasnodar, 350040, Russia

    N. D. Pismenskaya & K. A. Nebavskaya

Authors
  1. V. I. Vasil’eva
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  2. N. D. Pismenskaya
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  3. E. M. Akberova
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  4. K. A. Nebavskaya
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Correspondence to V. I. Vasil’eva.

Additional information

Original Russian Text © V.I. Vasil’eva, N.D. Pismenskaya, E.M. Akberova, K.A. Nebavskaya, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, Nos. 7–8, pp. 1114–1120.

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Vasil’eva, V.I., Pismenskaya, N.D., Akberova, E.M. et al. Effect of thermochemical treatment on the surface morphology and hydrophobicity of heterogeneous ion-exchange membranes. Russ. J. Phys. Chem. 88, 1293–1299 (2014). https://doi.org/10.1134/S0036024414080317

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  • DOI: https://doi.org/10.1134/S0036024414080317

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