Skip to main content
SpringerLink
Log in

Oxidative dehydrogenation of C2–C4 alkanes into alkenes: Conventional catalytic systems and microwave catalysis

  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Catalytic systems for the nonoxidative or oxidative dehydrogenation of C2–C4 alkanes into the respective alkenes are considered. Scanty data concerning microwave activation of these processes and the potential and advantages of microwave versus conventional technologies are analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. M. Zhorov, Thermodynamics of Chemical Processes (Khimiya, Moscow, 1985) [in Russian].

    Google Scholar 

  2. T. G. Alkhazov and A. E. Lisovskii, Oxidative Dehydrogenation of Hydrocarbons (Khimiya, Moscow, 1980) [in Russian].

    Google Scholar 

  3. V. K. Skarchenko, Dehydrogenation of Hydrocarbons (Naukova Dumka, Kiev, 1981) [in Russian].

    Google Scholar 

  4. US Patent No. 3119111 (1961).

  5. G. A. Stepanov, A. L. Kailingol’d, et al., Neftekhimiya 15, 815 (1965).

    Google Scholar 

  6. G. A. Stepanov and A. L. Caylingol’d, Synth. Rubber., p. 681 (1976).

  7. V. A. Doroshenko, L. R. Shapovalova, and D. N. Tmenov, Neftekhimiya 26, 48 (1986).

    CAS  Google Scholar 

  8. V. A. Doroshenko, L. R. Shapovalova, and D. N. Tmenov, Zh. Prikl. Khim. 55, 80 (1982).

    CAS  Google Scholar 

  9. USSR Patent No. 4899003 (1980).

  10. Yu. I. Panteleeva, A. M. Murzaev, and R. M. Talishinskii, Kinet. Katal. 32, 571 (1989).

    Google Scholar 

  11. D. P. Belomestnykh and O. K. Bogdanova, Neftekhimiya 15, 544 (1967).

    Google Scholar 

  12. USSR Patent No. 522851 (1976).

  13. I. P. Belomestnykh, E. A. Skrigan, N. N. Rozhdestvenskaya, and G. V. Isaguliants, Stud. Surf. Sci. Catal. 72, 416 (1992).

    Google Scholar 

  14. H. H. Kung, Adv. Catal. 40, 1 (1994).

    Article  CAS  Google Scholar 

  15. H. H. Kung and M. C. Kung, Appl. Catal. 157, 105 (1997).

    Article  CAS  Google Scholar 

  16. S. Albonetti, F. Cavani, and F. Trifiro, Catal. Rev. Sci. Eng. 38, 413 (1996).

    Article  CAS  Google Scholar 

  17. M. C. Abello, M. F. Gomez, and L. E. Cadus, Catal. Lett. 53, 185 (1998).

    Article  CAS  Google Scholar 

  18. E. M. Torsteinson, T. P. Wilson, F. G. Young, and P. H. Kasai, J. Catal. 52, 116 (1978).

    Article  Google Scholar 

  19. J. G. Ommen and J. R. H. Ross, Catal. Today 13, 620 (1992).

    Google Scholar 

  20. H. Swaan, A. Toebes, K. Seshan, et al., Catal. Today 13, 620 (1992).

    Google Scholar 

  21. US Patent No. 4450313 (1984).

  22. Y. Murakami, K. Otsuka, et al., Bull. Chem. Soc. Jpn. 63, 340 (1990).

    Article  CAS  Google Scholar 

  23. U. Takita, K. Kurasaki, U. Mizuhara, and T. Ishihara, Chem. Lett. 2, 335 (1993).

    Article  CAS  Google Scholar 

  24. O. J. Velle, A. Andersen, and K. J. Jens, Catal. Today 6, 567 (1990).

    Article  CAS  Google Scholar 

  25. Z. Huang, J. Yang, and G. Zhang, Chem. Abstr. 110, 154918 (1989).

    Google Scholar 

  26. R. H. H. Smits, R. Seshan, and J. R. H. Ross, Stud. Surf. Sci. Catal. 72, 221 (1992).

    Article  CAS  Google Scholar 

  27. D. Sam, V. Soenen, and J. C. Volta, J. Catal. 123, 417 (1990).

    Article  CAS  Google Scholar 

  28. G. Bellussi and G. Centi, Prepr. Am. Chem. Soc., Div. Pet. Chem. 37, 1242 (1975).

    Google Scholar 

  29. USA Patent No. 3784485 (1975).

  30. L. E. Cadus, M. C. Abello, M. F. Gome, and J. B. Rivarola, Ind. Eng. Chem. Res. 35, 14 (1996).

    Article  CAS  Google Scholar 

  31. A. Andersson, S. L. T. Andersson, G. Centi, et al., in Proceedings of the 10th International Congress on Catalysis (Budapest, 1992).

  32. S. Ushkov, Kinet. Katal. 29, 195 (1988).

    Google Scholar 

  33. M. Huff and L. D. Schmidt, Phys. Chem. 97, 11815 (1993).

    Article  CAS  Google Scholar 

  34. M. Huff and L. D. Schmidt, Catal. Today 21, 443 (1994).

    Article  Google Scholar 

  35. C. Yokoyama, S. Bharadwaj, and L. D. Schmodt, Catal. Lett. 38, 181 (1996).

    Article  CAS  Google Scholar 

  36. M. Huff and L. D. Schmidt, J. Catal., No. 1, 127 (1994).

  37. A. G. Dietz, A. F. Carlsson, and L. D. Schmidt, J. Catal. 176, 459 (1996).

    Article  Google Scholar 

  38. M. Huff and L. D. J. Schmidt, J. Catal. 155, 82 (1995).

    Article  CAS  Google Scholar 

  39. T. Faravelli, A. Goldanigo, E. Ranzi, et al., in Proceedings of the 5th NGS Giardini Naxos-Taormina (1998), p. 101

  40. A. S. Bodke, S. S. Bharadwaj, and L. D. Schmidt, J. Catal. 179, 138 (1998).

    Article  CAS  Google Scholar 

  41. US Patent No. 5639929 (1997).

  42. J. N. Michaels, D. L. Stern, and R. K. Grasselli, Catal. Lett. 42, 139 (1996).

    Article  CAS  Google Scholar 

  43. A. Pantazidis and C. Mirodatos, Stud. Surf. Sci. Catal. 101, 1029 (1996).

    Article  CAS  Google Scholar 

  44. A. Dejoz, J. M. Lopez-Nieto, F. Melo, and I. Varquez, Ind. Eng. Chem. Res. 36, 2588 (1997).

    Article  CAS  Google Scholar 

  45. M. C. Kung and H. H. Kung, J. Catal. 34, 668 (1992).

    Article  Google Scholar 

  46. A. Burrows, Ch. J. Kiely, J. Perregaard, et al., Catal. Lett. 57, 121 (1999).

    Article  CAS  Google Scholar 

  47. M. A. Chaar, D. Patel, and H. H. Kung, J. Catal. 109, 463 (1998).

    Article  Google Scholar 

  48. X. Gao, P. Ruiz, G. Xin, et al., J. Catal. 148, 56 (1994).

    Article  CAS  Google Scholar 

  49. S. R. G. Carrazan, C. Peres, and V. J. Delmon, J. Catal. 37, 241 (1996).

    Google Scholar 

  50. A. Corma, J. M. Lopez, N. Paredes, and I. Vazquez, New Developments in Selective Oxidation (Elsevier Science, Amsterdam, 1994), Vol. 82, p. 113.

    Google Scholar 

  51. P. Concepción, J. M. López-Nieto, and J. Pérez-Pariente, Catal. Lett. 19, 333 (1993).

    Article  Google Scholar 

  52. A. G. Ruiz, I. R. Ramos, J. L. G. Fierro, and V. J. Soenen, Stud. Surf. Sci. Catal. 72, 203 (1992).

    Article  Google Scholar 

  53. E. A. Mamedov, R. M. Talishinskii, R. G. Rizayev, et al., Catal. Today 32, 177 (1966).

    Article  Google Scholar 

  54. A. Corma, J. M. Lopez, N. Paredes, et al., New Developments in Selective Oxidation by Heterogeneous Catalysis (Elsevier Science, Amsterdam, 1992), p. 213.

    Book  Google Scholar 

  55. D. L. Stern, J. N. Michaels, L. Decaul, and R. K. Grasselli, Appl. Catal. 153, 21 (1997).

    Article  CAS  Google Scholar 

  56. R. X. Valenzuela, F. Arena, N. Giorno, and A. Parmaliana, J. Catal. 167, 296 (1997).

    Article  Google Scholar 

  57. P. M. Michalakos, M. C. Kung, I. Jahan, and H. H. Kung, J. Catal. 140, 226 (1992).

    Article  Google Scholar 

  58. A. Parmaliana, V. Sokolovskii, F. Arena, et al., Catal. Lett. 40, 105 (1966).

    Article  Google Scholar 

  59. G. Busca, E. Finocchhio, V. Lorenzelli, et al., Catal. Today 49, 453 (1999).

    Article  CAS  Google Scholar 

  60. S. R. Mirzabekova, A. Kh. Mamedov, V. S. Aliev, and O. V. Krylov, React. Kinet. Catal. Lett. 47, 159 (1992).

    Article  CAS  Google Scholar 

  61. S. R. Mirzabekova, A. Kh. Mamedov, V. S. Aliev, and O. V. Krylov, Kinet. Katal. 35, 271 (1994).

    CAS  Google Scholar 

  62. O. V. Krylov and A. Kh. Mamedov, Russ. Chem. Rev. 64, 877 (1995).

    Article  Google Scholar 

  63. S. Sato, M. Ohhara, T. Sodesawa, and F. Nozaki, Appl. Catal. 37, 207 (1988).

    Article  CAS  Google Scholar 

  64. G. Towler and S. Lynn, Chem. Eng. Sci. 49, 2585 (1994).

    Article  CAS  Google Scholar 

  65. P. Beato, A. Blume, F. Girgsdies, et al., Appl. Catal. 307, 137 (2006).

    Article  CAS  Google Scholar 

  66. B. Solsona, V. A. Zazhigalov, J. M. López-Nieto, et al., Appl. Catal. 249, 81 (2003).

    Article  CAS  Google Scholar 

  67. US Patent No. 6891075 (2005).

  68. US Patent No. 4524236 (1985).

  69. US Patent No. 4899003 (1990).

  70. US Patent No. 6624116 (2003).

  71. US Patent No. 6566573 (2003).

  72. J. M. Lopez-Nieto, P. Botella, M. I. Vazquez, and A. Dejoz, Chem. Commun., p. 1906 (2002).

  73. US Patent Application No. 0085678 (2005).

  74. Patent WO No. 03/064035 (2003).

  75. Microwave Power Engineering, Vol. 1: Generation, Transmission, Rectification, Ed. by E. C. Okress (Academic, New York, 1968; Mir, Moscow, 1971).

    Google Scholar 

  76. B. Ondrushka, Chem. Eng. Technol. 27, 2 (2004).

    Google Scholar 

  77. J. K. S. Wan, M. Y. Tse, and M. C. Depew, US Patent No. 5215634 (1993).

  78. G. Bond, R. B. Moyes, and D. A. Whan, Catal. Today 17, 427 (1993).

    Article  CAS  Google Scholar 

  79. Z. M. Yang, J. S. Zhang, X. M. Cao, et al., Appl. Catal. B 34, 129 (2001).

    Article  CAS  Google Scholar 

  80. Y. Liu, Y. Lu, S. M. Liu, and Y. Q. Yin, Catal. Today 51, 147 (1999).

    Article  CAS  Google Scholar 

  81. C. L. Chen, P. J. Hong, S. S. Dai, et al., React. Kinet. Catal. Lett. 61, 181 (1997).

    Article  CAS  Google Scholar 

  82. C. L. Chen, P. J. Hong, S. S. Dai, et al., React. Kinet. Catal. Lett. 61, 175 (1997).

    Article  CAS  Google Scholar 

  83. L. D. Conde, C. Marun, S. L. Suib, and Z. Fathi, J. Catal. 204, 324 (2001).

    Article  CAS  Google Scholar 

  84. A. Wali, S. M. Pillai, and S. Satish, React. Kinet. Catal. Lett. 60, 189 (1997).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. M. Kustov, A. V. Kucherov & E. D. Finashina

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    L. M. Kustov

Authors
  1. L. M. Kustov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Kucherov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. D. Finashina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. M. Kustov.

Additional information

Original Russian Text © L.M. Kustov, A.V. Kucherov, E.D. Finashina, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 3, pp. 357–363.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kustov, L.M., Kucherov, A.V. & Finashina, E.D. Oxidative dehydrogenation of C2–C4 alkanes into alkenes: Conventional catalytic systems and microwave catalysis. Russ. J. Phys. Chem. 87, 345–351 (2013). https://doi.org/10.1134/S0036024413030151

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024413030151

Keywords

Search

Navigation