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Cerium(IV) Orthophosphates (Review)

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

The review analyzes the data on the composition, structure, and properties of amorphous and crystalline cerium(IV) orthophosphates published between 1882 and 2020. The review includes information on Ce(IV) complexation in aqueous solutions, formation conditions and characteristics of amorphous inorganic and organo-inorganic cerium(IV) hydrogen orthophosphates, and structural diversity of crystalline cerium(IV) orthophosphates. Formation conditions and structure of the closest chemical analogs of cerium(IV) orthophosphates, Group IV metal and actinide (thorium and uranium) orthophosphates, have been compared for the first time; the comparison provided a basis to assess the possibilities to prepare isostructural cerium(IV) compounds unknown to date.

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Notes

  1. Crystal structure parameters presented in this review are given in the summary table “Composition and structural parameters of cerium(IV) orthophosphates and their isostructural analogs” (Table 1).

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This work was financially supported by the Russian Foundation for Basic Research (project no. 20-13-50117).

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    T. O. Kozlova, A. E. Baranchikov & V. K. Ivanov

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Kozlova, T.O., Baranchikov, A.E. & Ivanov, V.K. Cerium(IV) Orthophosphates (Review). Russ. J. Inorg. Chem. 66, 1761–1778 (2021). https://doi.org/10.1134/S003602362112010X

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