Skip to main content
Log in

Production of carbon nano- and microfibers by methane pyrolysis on zirconia

  • Physical Methods of Investigation
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The production of carbon nano- and microfibers by pyrolysis of methane (mains gas) on three ZrO2 samples prepared by different methods, at 400–700°C, methane flow rates of 175–1050 mL/min, and process times up to 4 h was studied. Comparatively long carbon bamboo-like microfibers having diameters of 0.24–0.31 μm were found to form on ZrO2, their weights and linear growth rates were assessed, and the process was shown to not slow down over time. The electrical conductivities of the fibers were measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. G. Rakov, Nanotubes and Fullerenes (Universitetskaya Kniga, Logos, Moscow, 2006) [in Russian].

    Google Scholar 

  2. C. F. Curtis, Acta Crystallogr. 12, 382 (1959).

    Article  Google Scholar 

  3. M. Inagaki, Material Science and Engineering of Carbon: Fundamentals, 2nd Ed. (Elsevier, 2014).

    Google Scholar 

  4. M. H. Rümmeli, C. Kramberger, A. Grüneis, et al., Chem. Mater. 19, 4105 (2007).

    Article  Google Scholar 

  5. H. Liu, D. Takagi, H. Ohno, et al., Appl. Phys. Express 1, 014001 (2008).

    Article  Google Scholar 

  6. B. Liu, W. Ren, L. Gao, et al., J. Am. Chem. Soc. 131, 2082 (2009).

    Article  CAS  Google Scholar 

  7. S. A. Steiner, T. F. Baumann, B. C. Bayer, et al., J. Am. Chem. Soc. 131, 12144 (2009).

    Article  CAS  Google Scholar 

  8. T. Y. Luo, T. X. Liang, and C. S. Li, Mater. Sci. Eng., A 366, 206 (2004).

    Article  Google Scholar 

  9. G. Gonzalez, C. Albano, V. Herman, et al., Mater. Charact. 64, 96 (2012).

    Article  CAS  Google Scholar 

  10. A. Kudo, S. A. Steiner, III, B. C. Bayer, et al., J. Am. Chem. Soc. 136, 17808 (2014).

    Article  CAS  Google Scholar 

  11. A. Yamaguchi, S. Zhang, and J. Yu, J. Am. Ceram. Soc. 79, 2509 (1996).

    Article  CAS  Google Scholar 

  12. T. H. Nguyen, M. T. Nguyen, and E. G. Rakov, Inorg. Mater. 46, 1077 (2010).

    Article  CAS  Google Scholar 

  13. H. V. Nguyen, S. T. Luu, and E. G. Rakov, Inorg. Mater. 48, 128 (2012).

    Article  CAS  Google Scholar 

  14. E. R. Meshot, D. L. Plata, S. Tawfick, et al., ACS Nano 3, 2477 (2009).

    Article  CAS  Google Scholar 

  15. M. Saeidi and M. Vaezzadeh, Iran. J. Sci. Technol. A, 1 29 (2011).

    Google Scholar 

  16. G. Chen, R. C. Davis, H. Kimura, et al., Nanoscale 7, 8873 (2015).

    Article  CAS  Google Scholar 

  17. V. Jourdain and C. Bichara, Carbon 58, 2 (2013).

    Article  CAS  Google Scholar 

  18. Y. Saito and T. Yoshikawa, J. Crystal Growth 134, 154 (1993).

    Article  CAS  Google Scholar 

  19. M. Lin, J. P. Y. Tan, C. Boothroyd, et al., Nano Lett. 7, 2234 (2007).

    Article  CAS  Google Scholar 

  20. L.-L. Tan, W.-J. Ong, S.-P. Chai, and A. R. Mohamed, Catal. Today 217, 1 (2013).

    Article  CAS  Google Scholar 

  21. O. E. Glukhova, A. S. Kolesnikova, G. V. Torgashev, and Z. I. Buyanova, Fiz. Tverd. Tela 52, 1240 (2010).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. G. Rakov.

Additional information

Original Russian Text © Sh.T. Lyu, E.G. Rakov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 1, pp. 92–96.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lyu, S.T., Rakov, E.G. Production of carbon nano- and microfibers by methane pyrolysis on zirconia. Russ. J. Inorg. Chem. 62, 94–98 (2017). https://doi.org/10.1134/S0036023617010193

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023617010193

Navigation