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Coordination modes of α-dioximes in uranyl complexes

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Abstract

α-Dioximes are well-known analytical reagents that comprise two oxime groups. Such ligands have been widely used in the recovery and separation and in analytical determination of d-transition elements. This survey deals with uranyl complexes with α-dioximes, which constitute a new class of uranium(VI) coordination compounds and are distinguished from the other transition-metal glyoximates by unusual coordination modes of the ligand to the central atom.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. G. Beirakhov, I. M. Orlova & Yu. N. Mikhailov

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  1. A. G. Beirakhov
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  2. I. M. Orlova
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  3. Yu. N. Mikhailov
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Correspondence to A. G. Beirakhov.

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Beirakhov, A.G., Orlova, I.M. & Mikhailov, Y.N. Coordination modes of α-dioximes in uranyl complexes. Russ. J. Inorg. Chem. 59, 1679–1690 (2014). https://doi.org/10.1134/S0036023614140022

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