Abstract
Glasses have been prepared in the InF3-BiF3-BaF2-PbF2-ZnF2-LnF3 (Ln = Eu, Tm) system. The short-range and medium-range order structure of the glass network is discussed on the basis of IR and Raman spectroscopy data. The effect of bismuth trifluoride on the thermal properties, structure, and photo-luminescence properties of glasses was studied. Bismuth trifluoride doping improves the thermal parameters of glasses. The polyhedra formed by bismuth trifluoride in the glass are not involved in the medium-range order. In rare-earth-containing glasses, strong photoluminescence was discovered in the range 530–560 nm with excitation by the Raman-masking 532-nm wavelength. Bismuth in the glass enhances the europium photoluminescence level in the glass of the InF3-BiF3-BaF2-PbF2-ZnF2-EuF3 system.
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Original Russian Text © L.N. Ignatieva, N.V. Surovtsev, E.B. Merkulov, N.N. Savchenko, S.V. Adishchev, Yu.V. Marchenko, V.M. Bouznik, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 2, pp. 179–185.
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Ignatieva, L.N., Surovtsev, N.V., Merkulov, E.B. et al. InF3-based bismuth-containing glasses. Russ. J. Inorg. Chem. 57, 139–145 (2012). https://doi.org/10.1134/S003602361202012X
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DOI: https://doi.org/10.1134/S003602361202012X