Abstract
A solvated form of zinc dimethyldithiocarbamate adduct with piperidine of the composition [Zn{NH(CH2)5}{S2CN(CH3)2}2] · 2C6H5CH3 (I) was synthesized. The structure and thermal properties of the adduct were studied by X-ray crystallography and simultaneous thermal analysis (STA). The structure of compound I is characterized by the presence of a system of channels populated by solvating toluene molecules (structural type of lattice clathrates). The central zinc atom coordinates two dithiocarbamate ligands and a piperidine molecule (zinc coordination number CNZn = 5). The zinc polyhedron geometry is intermediate between a tetragonal pyramid (TP) and trigonal bipyramid (TBP); the contributions of the TP and TBP components were evaluated from the X-ray diffraction data. The STA study of the thermal properties of I has shown that the weight loss occurs in three steps and includes desorption of solvating toluene molecules, then, desorption of coordinated piperidine molecules, and thermolysis of the dithiocarbamate moiety of the complex with formation of a zinc sulfate powder.
Similar content being viewed by others
References
A. V. Ivanov, V. I. Mitrofanova, M. Kritikos, and O. N. Antzutkin, Polyhedron 18(15), 2069 (1999).
A. V. Ivanov and O. N. Antzutkin, Polyhedron 21(27–28), 2727 (2002).
A. V. Ivanov, W. Forsling, M. Kritikos, et al., Dokl. Akad. Nauk 369(1–3), 64 (1999) [Dokl. Chem. 369 (1), 268 (1999)].
A. V. Ivanov, M. Kritikos, O. N. Antzutkin, and W. Forsling, Inorg. Chim. Acta 321(1–2), 63 (2001).
A. V. Ivanov, A. S. Zaeva, A. V. Gerasimenko, and V. Forsling, Dokl. Akad. Nauk 404(4), 505 (2005) [Dokl. Phys. Chem. 404 (2), 205 (2005)].
A. V. Ivanov, A. S. Zaeva, E. V. Novikova, et al., Koord. Khim. 33(4), 243 (2007) [Russ. J. Coord. Chem. 33 (4), 233 (2007)].
A. V. Ivanov, I. A. Lutsenko, and W. Forsling, Koord. Khim. 28(1), 60 (2002) [Russ. J. Coord. Chem. 28 (1), 57 (2002)].
A. V. Ivanov, M. Kritikos, A. Lund, et al., Zh. Neorg. Khim. 43(9), 1482 (1998) [Russ. J. Inorg. Chem. 43 (9), 1368 (1998)].
A. V. Ivanov, M. Kritikos, O. N. Antzutkin, et al., Koord. Khim. 24(9), 689 (1998) [Russ. J. Coord. Chem. 24 (9), 645 (1998)].
A. V. Ivanov, S. A. Leskova, M. A. Mel’nikova, et al., Zh. Neorg. Khim. 48(3), 462 (2003) [Russ. J. Inorg. Chem. 48 (3), 415 (2003)].
A. V. Ivanov, W. Forsling, O. N. Antzutkin, et al., Dokl. Akad. Nauk 366(5), 643 (1999) [Dokl. Chem. 366 (4–6), 142 (1999)].
A. V. Ivanov, M. Kritikos, O. N. Antsutkin, et al., Koord. Khim. 25(8), 583 (1999) [Russ. J. Coord. Chem. 25 (8), 543 (1999)].
A. V. Ivanov, M. Kritikos, O. N. Antzutkin, and A. Lund, Zh. Neorg. Khim. 44(10), 1689 (1999) [Russ. J. Inorg. Chem. 44 (10), 1605 (1999)].
A. V. Ivanov, A. S. Zaeva, A. V. Gerasimenko, and T. A. Rodina, Koord. Khim. 34(9), 696 (2008) [Russ. J. Coord. Chem. 34 (9), 688 (2008)].
A. S. Zaeva, Vestnik AmGU 43, 72 (2008).
Bruker SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Madison (WI, USA): Bruker AXS, 1998.
Bruker SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data. Madison (WI, USA): Bruker AXS, 1998.
A. W. Addison, T. N. Rao, J. Reedijk, et al., J. Chem. Soc., Dalton Trans., No. 7, 1349 (1984).
A. V. Ivanov, V. I. Palazhchenko, S. A. Leskova, and M. A. Mel’nikova, Zh. Neorg. Khim. 50(7), 1101 (2005) [Russ. J. Inorg. Chem. 50 (7), 1014 (2005)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Zaeva, T.A. Rodina, A.V. Ivanov, A.V. Gerasimenko, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 8, pp. 1388–1393.
Rights and permissions
About this article
Cite this article
Zaeva, A.S., Rodina, T.A., Ivanov, A.V. et al. Toluene-solvated zinc dimethyldithiocarbamate adduct with piperidine [Zn{NH(CH2)5}{S2CN(CH3)2}2] · 2C6H5CH3: Synthesis, structure, and thermal properties. Russ. J. Inorg. Chem. 56, 1318–1323 (2011). https://doi.org/10.1134/S0036023611080286
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023611080286