Skip to main content
SpringerLink
Log in

Effect of the Porphyrin Structure on the Kinetics of Complex Formation with Zinc Dipyrromethene in Dimethylformamide

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The kinetics of complex formation of zinc dipyrromethene with tetraphenylporphyrin, octaethylporphyrin, and 5,15-dipentyl-2,3,7,8,12,13,17,18-octamethylporphine at 368–420 K have been studied. The kinetic parameters (k app, k v) of the complex formation processes have been determined. The porphyrin molecules have been optimized by the PM3 quantum-chemical method, and their geometric characteristics have been obtained. The effect of the structure and macrocycle strain of porphyrins on the complex formation rate is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. M. Mamardashvili, Zh. Neorg. Khim. 48(3), 512 (2003) [Russ. J. Inorg. Chem. 48 (3), 439 (2003)].

    CAS  Google Scholar 

  2. S. V. Zaitseva, S. A. Zdanovich, and O. I. Koifman, Zh. Neorg. Khim. 48(1), 137 (2003) [Russ. J. Inorg. Chem. 48 (1), 128 (2003)].

    CAS  Google Scholar 

  3. S. A. Zdanovich, T. A. Ageeva, O. A. Golubchikov, and A. S. Semeikin, Koord. Khim. 27(3), 168 (2001).

    Google Scholar 

  4. D. Dolphin, J. Heterocycl. Chem. 1(2), 275 (1970).

    Article  Google Scholar 

  5. A. Treibs and N. Hoberle, Liebigs Ann. Chem. 718, 183 (1968).

    Article  CAS  Google Scholar 

  6. S. A. Zdanovich, N. Zh. Mamardashvili, and O. A. Golubchikov, Zh. Org. Khim. 32(2), 788 (1996).

    CAS  Google Scholar 

  7. A. V. Glazunov and A. S. Semeikin, USSR Inventor’s Certificate No. 1578129, Byull. Izobret., No. 26 (1990).

  8. A. J. Gordon and R. A. Ford, The Chemist’s Companion: A Handbook of Practical Data, Techniques and References (Wiley, New York, 1972; Mir, Moscow, 1976).

    Google Scholar 

  9. Experimental Techniques of Chemical Kinetics, Ed. by N. M. Emanuel’ and G. B. Sergeev (Vysshaya Shkola, Moscow, 1980) [in Russian].

  10. I. B. Bersuker, The Electronic Structure and Properties of Coordination Compounds (Khimiya, Leningrad, 1986) [in Russian].

    Google Scholar 

  11. M. W. Schmidt and K. K. Baldridge, J. Comput. Chem. 14, 1347 (1993).

    Article  CAS  Google Scholar 

  12. J. J. P. Stewart, J. Computer-Aided Mol. Des. 4, 105 (1990).

    Article  Google Scholar 

  13. R. Fletcher, Methods of Optimization (Wiley, New York, 1980).

    Google Scholar 

  14. B. D. Berezin, Coordination Compounds of Porphyrins and Phthalocyanine (Nauka, Moscow, 1978; Wiley, New York, 1981).

    Google Scholar 

  15. G. M. Mamardashvili and B. D. Berezin, Koord. Khim. 26(9), 699 (2000).

    Google Scholar 

  16. B. D. Berezin and G. M. Mamardashvili, Koord. Khim. 26(10), 796 (2002).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. R. Simonova, S. V. Zaitseva & O. I. Koifman

  2. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    O. I. Koifman

Authors
  1. O. R. Simonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Zaitseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. I. Koifman
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Simonova, O.R., Zaitseva, S.V. & Koifman, O.I. Effect of the Porphyrin Structure on the Kinetics of Complex Formation with Zinc Dipyrromethene in Dimethylformamide. Russ. J. Inorg. Chem. 53, 391–396 (2008). https://doi.org/10.1134/S0036023608030091

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023608030091

Keywords

Search

Navigation