Skip to main content
SpringerLink
Log in

Silicon-containing hydroxylapatite nanopowders

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Silicon-substituted hydroxylapatite nanopowders containing 0.14–1.4 wt % Si have been synthesized by the heterophase reaction between calcium hydroxide, diammonium hydrogen phosphate, tetraethoxysilane, and water and by precipitation from aqueous solutions of calcium nitrate, diammonium hydrogen phosphate, and tetraethoxysilane. The products have been characterized by specific surface area (S BET) measurements, X-ray powder diffraction, chemical analysis, and IR spectroscopy. The phase composition of the products depends on the synthesis method. The heterophase reaction yields nanopowders with S BET = 20–24 m2/g in which the main crystalline phase is silicon-substituted hydroxylapatite. The product synthesized by precipitation from solution has an S BET of up to 73 m2/g and an increased tricalcium phosphate content, which crystallizes from the amorphous phase during heat treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Aoki, Science and Medical Application of Hydroxyapatite (JAAS, Tokyo, 1991).

    Google Scholar 

  2. A. G. Veresov, V. I. Putlyaev, and Yu. D. Tret’yakov, Ross. Khim. Zh. 44(6) (2000).

  3. A. I. Volozhin, S. G. Kurdyumov, V. P. Orlovskii, S. M. Barinov, et al., Tekhnol. Zhivykh Sistem 1(1), 41 (2004).

    CAS  Google Scholar 

  4. N. Patel, I. R. Gibson, K. A. Hing, S. M. Best, et al., J. Mater. Sci. Mater. Med. 13, 1199 (2002).

    Article  CAS  Google Scholar 

  5. A. E. Porter, N. Patel, J. N. Skepper, S. M. Best, et al., Biomaterials 25, 3303 (2004).

    Article  CAS  Google Scholar 

  6. K. Schwarz and S. C. Chen, Fed. Proc. 33, 704 (1974).

    Google Scholar 

  7. A. E. Porter, N. Patel, J. N. Skepper, S. M. Best, et al., Biomaterials 24, 4609 (2003).

    Article  CAS  Google Scholar 

  8. N. Patel, R. A. Brooks, M. T. Clarke, et al., J. Mater. Sci. Mater. Med. 16, 429 (2005).

    Article  CAS  Google Scholar 

  9. I. R. Gibson, S. M. Best, and W. Bonfield, J. Biomed. Mater. Res. 44, 422 (1999).

    Article  CAS  Google Scholar 

  10. S. Zou, J. Huang, S. Best, and W. Bonfield, J. Mater. Sci. Mater. Med. 16, 1143 (2005).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physicochemical Problems of Ceramic Materials, Russian Academy of Sciences, ul. Ozernaya 48, Moscow, 119361, Russia

    N. V. Bakunova, A. S. Fomin, I. V. Fadeeva, S. M. Barinov & L. I. Shvorneva

Authors
  1. N. V. Bakunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Fomin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Fadeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. M. Barinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. I. Shvorneva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. M. Barinov.

Additional information

Original Russian Text © N.V. Bakunova, A.S. Fomin, I.V. Fadeeva, S.M. Barinov, L.I. Shvorneva, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 10, pp. 1594–1599.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bakunova, N.V., Fomin, A.S., Fadeeva, I.V. et al. Silicon-containing hydroxylapatite nanopowders. Russ. J. Inorg. Chem. 52, 1492–1497 (2007). https://doi.org/10.1134/S0036023607100026

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023607100026

Keywords

Search

Navigation