Abstract
The solubilities of hydrogen sulfide expressed in mole fractions may be related, through multiparameter equations, to parameters that account for the specific and nonspecific solvation ability of the solvent and for the cohesion energy. The key factors are the self-association of the solvent, which reduces the solubility, and the complexing ability with hydrogen sulfide, which increases the solubility.
Similar content being viewed by others
References
A. L. Kohl and F. C. Riesenfeld, Gas Purification (Gulf Publishing Co., Houston, 1985; Nedra, Moscow, 1968).
F. Rosendahl, Erdol Kohle 34(3), 132 (1981).
L. Gazzi, D. Sguera, and C. Rescalli, Erdol Kohle 39(9), 415 (1986).
B. P. Bell, J. Chem. Soc., 1371 (1931).
W. Gerrard, J. Appl. Chem. Biotechnol. 22(5), 623 (1972).
J. Makranczy, K. Megyery-Balog, L. Rusz, and L. Patyi, Hungar. J. Ind. Chem. 4(4), 269 (1976).
D. V. Bryk, R. G. Makitra, Ya. N. Pirig, and Yu. V. Stefanyk, Zh. Prikl. Khim. 61(1), 91 (1988).
D. V. Bryk, R. G. Makitra, Ya. N. Pirig, and Yu. V. Stefanyk, Zh. Prikl. Khim. 63(2), 302 (1990).
Ya. N. Pirig, R. G. Makitra, and I. P. Polyuzhin, Zh. Prikl. Khim. 66(4), 835 (1993).
R. G. Makitra, F. B. Moin, Ya. N. Pirig, and T. I. Politanskaya, Zh. Prikl. Khim. 53(7), 1529 (1980).
R. G. Makitra, T. I. Politanskaya, F. B. Moin, et al., Zh. Prikl. Khim. 56(10), 2205 (1983).
V. A. Pal’m, Principles of Quantitative Theory of Organic Reactions (Khimiya, Leningrad, 1977) [in Russian].
R. G. Makitra, Ukr. Khim. Zh. 58(2), 260 (1992).
J. L. M. Abboud and R. Notario, Pure Appl. Chem. 71(4), 645 (1999).
R. G. Makitra, Ya. N. Pirig, and R. B. Kivelyuk, available from VINITI, No. 625-V86 (1985).
K. K. Tremper and J. M. Prausnitz, J. Chem. Eng. Data 21(3), 295 (1976).
G. G. Devyatykh, A. E. Ezheleva, A. D. Zorin, and M. V. Zueva, Zh. Neorg. Khim. 8(6), 1307 (1963).
S. V. Shakhova, T. I. Bondareva, and Yu. P. Zubchenko, Khim. Prom-st. 42(10), 753 (1966).
S. V. Shakhova, T. I. Bondareva, and L. E. Sergeeva, Khim. Prom-st. 42(7), 516 (1966).
P. L. Yarym-Agaev, V. G. Matvienko, and I. V. Povalyaeva, Zh. Prikl. Khim. 53(11), 2456 (1980).
I. E. Furmer, V. M. Gudasheva, and F. M. Khutoryanskii, Khim. Prom-st. 46(12), 898 (1970).
J. Y. Lenoir, P. Renault, and H. Renon, J. Chem. Eng. 16(3), 340 (1971).
Author information
Authors and Affiliations
Additional information
Original Russian Text © S.D. Bryk, R.G. Makitra, E.Ya. Pal’chikova, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 3, pp. 555–560.
Rights and permissions
About this article
Cite this article
Bryk, S.D., Makitra, R.G. & Pal’chikova, E.Y. Solubility of hydrogen sulfide in organic solvents. Russ. J. Inorg. Chem. 51, 506–511 (2006). https://doi.org/10.1134/S0036023606030296
Received:
Issue Date:
DOI: https://doi.org/10.1134/S0036023606030296