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Kinetic Regularities of the Kabachnik–Fields Reaction under Catalysis by Sulfonic Cation Exchangers Based on Petroleum Asphaltenes

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Abstract

Strongly acidic cation exchangers were obtained by the sulfonation and successive sulfonation and nitration of petroleum asphaltenes. The cation exchangers were characterized by IR spectroscopy and acid–base back titration; the surface morphology was studied by scanning electron microscopy. The kinetic regularities of the Kabachnik–Fields reaction were studied at various temperatures in the course of catalysis by the cation exchangers based on asphaltenes and in the absence of a catalyst.

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ACKNOWLEDGMENTS

We are grateful to the staff of the Distributed Collective Spectroanalytical Center for the Study of the Structure, Composition, and Properties of Substances and Materials of the FRC Kazan Scientific Center, Russian Academy of Sciences for performing the experimental studies.

Funding

This work was carried out within the framework of a state contract of the FRC Kazan Scientific Center, Russian Academy of Sciences.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    L. E. Foss, K. V. Shabalin, M. R. Yakubov & D. N. Borisov

Authors
  1. L. E. Foss
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  2. K. V. Shabalin
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  3. M. R. Yakubov
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  4. D. N. Borisov
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Correspondence to L. E. Foss.

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The authors declare that they have no conflicts of interest.

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Translated by V. Makhlyarchuk

Abbreviations and notation: SEC, static exchange capacity; DEP, diethyl phosphite; DAP, diethyl [1-(phenylamino)cyclohexyl]phosphonate.

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Foss, L.E., Shabalin, K.V., Yakubov, M.R. et al. Kinetic Regularities of the Kabachnik–Fields Reaction under Catalysis by Sulfonic Cation Exchangers Based on Petroleum Asphaltenes. Kinet Catal 63, 593–598 (2022). https://doi.org/10.1134/S0023158422050032

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  • DOI: https://doi.org/10.1134/S0023158422050032

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