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Allylic oxdation of alkenes with molecular oxygen catalyzed by porous coordination polymers Fe-MIL-101 and Cr-MIL-101

  • IX International Conference on Mechanisms of Catalytic Reactions (St. Petersburg, October 22–25, 2012)
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Abstract

The catalytic performances of Cr-MIL-101 and Fe-MIL-101 porous coordination polymers have been investigated in the allylic oxidation of alkenes, including natural terpenes, with molecular oxygen (1 atm) under mild solvent-free conditions. Both catalysts remain stable under optimal conditions (40°C for Fe-MIL-101 and 60°C for Cr-MIL-101) and can be recycled, at least, four times without loss of the catalytic properties. Fe-MIL-101 favours the formation of unsaturated alcohols, while Cr-MIL-101 mediates the formation of unsaturated ketones. The oxidation process involves the formation of alkene hydroperoxide via conventional radical chain process and its further transformations over the MIL-101 catalysts. The mechanism of the hydroperoxide transformation strongly depends on the metal nature.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    I. Yu. Skobelev & O. A. Kholdeeva

  2. Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON), UMR 5256, CNRS-Universite-Lyon 1, 2, av. A. Einstein, 69626, Villeurbanne Cedex, France

    I. Yu. Skobelev & A. B. Sorokin

  3. Nikolaev Institute of Inorganic Chemistry, Novosibirsk, 630090, Russia

    K. A. Kovalenko & V. P. Fedin

Authors
  1. I. Yu. Skobelev
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  2. K. A. Kovalenko
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  3. V. P. Fedin
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  4. A. B. Sorokin
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  5. O. A. Kholdeeva
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Correspondence to O. A. Kholdeeva.

Additional information

Published in Russian in Kinetika i Kataliz, 2013, Vol. 54, No. 5, pp. 641–648.

The article was translated by the authors.

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Skobelev, I.Y., Kovalenko, K.A., Fedin, V.P. et al. Allylic oxdation of alkenes with molecular oxygen catalyzed by porous coordination polymers Fe-MIL-101 and Cr-MIL-101. Kinet Catal 54, 607–614 (2013). https://doi.org/10.1134/S0023158413050169

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  • DOI: https://doi.org/10.1134/S0023158413050169

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