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Rate constant of the gas-phase reaction between Fe atoms and CO2

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Abstract

The rate constant of the gas-phase reaction Fe(a 5 D 4) + CO2 at 1180–2380 K and a total gas density of (7.0–10.0) × 10−6 mol/cm3 behind incident shock waves is k(Fe + CO2) = 1.4 × 1014.0 ± 0.3exp[−(14590 ± 1100)/T] cm3 mol−1 s−1, as determined by resonance atomic absorption photometry. Using thermochemical data available from the literature, the rate constant of the reverse reaction was calculated to be k(Fe + CO) = 9.2 × 1011.0 ± 0.3 (T/1000)0.57exp[−(490 ± 1100)/T] cm3 mol−1 s−1. The results are compared with data reported earlier.

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  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. N. Smirnov

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  1. V. N. Smirnov
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Correspondence to V. N. Smirnov.

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Original Russian Text © V.N. Smirnov, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 5, pp. 637–639.

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Smirnov, V.N. Rate constant of the gas-phase reaction between Fe atoms and CO2 . Kinet Catal 49, 607–609 (2008). https://doi.org/10.1134/S0023158408050017

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  • DOI: https://doi.org/10.1134/S0023158408050017

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