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SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE

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Abstract

By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp)– = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2·C6H6, and 3.

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Scheme 1
Scheme 2
Scheme 3
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Funding

The work was supported by the Russian Science Foundation (grant No. 16-13-10294).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    D. S. Kolybalov, T. S. Sukhikh, D. A. Bashirov & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    D. S. Kolybalov

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  1. D. S. Kolybalov
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  2. T. S. Sukhikh
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  3. D. A. Bashirov
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  4. S. N. Konchenko
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Correspondence to D. A. Bashirov.

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Translated from Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 2, pp. 292-300 https://doi.org/10.26902/JSC_id68354 .

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Kolybalov, D.S., Sukhikh, T.S., Bashirov, D.A. et al. SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE. J Struct Chem 62, 277–284 (2021). https://doi.org/10.1134/S0022476621020128

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