Skip to main content
SpringerLink
Log in

STRUCTURE AND LUMINESCENT PROPERTIES OF COORDINATION POLYMERS CONTAINING LEAD(II) AND THIOPHENE LIGANDS

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Three new metal-organic framework polymers [Pb2(btdc)2] (1), [Pb3(ttdc)3(dma)2] (2), and [Pb(ttdc)(dma)] (3) (H2btdc = 2,2′-bithiophene-5,5′-dicarboxylic acid, H2ttdc = thieno[3,2-b]thiophene-2,5-dicarboxylic acid, dma = N,N-dimethylacetamide) are synthesized under solvatothermal conditions. The compounds are characterized by single crystal and powder X-ray diffraction, elemental, thermogravimetric, and IR spectroscopic analyses. All three compounds are three-dimensional coordination polymers with layered (1) or chain (2, 3) motifs. The study of luminescent properties reveals the intraligand nature of radiative transitions. For 1 luminescence quenching is observed because of the strengthening of vibrational states and long-range interactions between π-systems of thiophene groups. The luminescence spectrum of 2 contains two bands corresponding to two types of ttdc2– ligands with principally different structural environments. For the ligands isolated from each other the position of the luminescence maximum corresponds to that of the free ttdc2– ion. For the ligands associated in closely packed chains by continuous π-stacking the appearance of a new maximum in the red range is observed, which is due to the delocalization of electron orbitals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

REFERENCES

  1. S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Pure Appl. Chem., 2017, 89, 1049–1064.

  2. M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Rev., 2018, 87(11), 1139–1167.

  3. D. N. Dybtsev, A. A. Sapianik, and V. P. Fedin. Mendeleev Commun., 2017, 27, 321–331.

  4. A. E. Baumann, D. A. Burns, B. Liu, and V. S. Thoi. Commun. Chem., 2019, 2, 86.

  5. S. Yuan, L. Feng, K. Wang, J. Pang, M. Bosch, C. Lollar, Y. Sun, J. Qin, X. Yang, P. Zhang, Q. Wang, L. Zou, Y. Zhang, L. Zhang, Y. Fang, J. Li, and H.-C. Zhou. Adv. Mater., 2018, 37, 1704303.

  6. Q. Wang and D. Astruc. Chem. Rev., 2020, 120, 1438–1511.

  7. X.-Y. Zhao, B. Liang, K.-C. Xiong, Y.-W. Shi, S.-L. Yang, T.-Y. Wei, H. Zhang, Q.-F. Zhang, and Y.-L. Gai. Dalton Trans., 2020, 49, 5695–5702.

  8. M. Yoon and D. Moon. Microporous Mesoporous Mater., 2017, 215, 116–122.

  9. S. Parshamoni and S. Konar. CrystEngComm, 2016, 18, 4395–4404.

  10. M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. Polyhedron, 2019, 162, 311–315.

  11. A. A. Lysova, D. G. Samsonenko, K. A. Kovalenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Bull., 2019, 68, 793–801.

  12. D. B. Mitzi. Prog. Inorg. Chem., 2007, 48, 1–121.

  13. C. C. Stoumpos, L. Mao, C. D. Malliakas, and M. G. Kanatzidis. Inorg. Chem., 2017, 56, 56–73.

  14. S. A. Adonin, L. A. Frolova, M. N. Sokolov, G. V. Shilov, D. V. Korchagin, V. P. Fedin, S. M. Aldoshin, K. J. Stevenson, and P. A. Troshin. Adv. Energy Mater., 2018, 8, 17001140.

  15. S. A. Adonin, M. N. Sokolov, and V. P. Fedin. Russ. J. Inorg. Chem., 2017, 62, 1789–1796.

  16. A. A. Lysova, D. G. Samsonenko, P. V. Dorovatovskii, V. A. Lazarenko, V. N. Khrustalev, K. A. Kovalenko, D. N. Dybtsev, and V. P. Fedin. J. Am. Chem. Soc., 2019, 141, 17260–17269.

  17. A. A. Sapianik, D. G. Samsonenko, K. A. Kovalenko, D. N. Dybtsev, M. Schröder, V. P. Fedin, E. N. Zorina-Tikhonova, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko, A. J. Blake, and S. P. Argent. Inorg. Chem., 2017, 56, 1599–1608.

  18. A. M. Samsonova, V. A. Bolotov, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. J. Struct. Chem., 2019, 60 (9), 1468–1473.

  19. J. D. Einkauf, R. E. Ortega, L. Mathivathanan, and D. T. de Lill. New J. Chem., 2017, 41, 10929–10934.

  20. CrysAlisPro 1.171.40.67a. Rigaku Oxford Diffraction: Woodlands, TX, USA, 2019.

  21. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2015, 71, 3–8.

  22. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3–8.

  23. C. R. Groom, I. J. Bruno, M. P. Lightfoot, and S. C. Ward. Acta Crystallogr., 2016, 72, 171–179.

  24. D. Sahoo, K. Sugiyasu, Y. Tian, M. Takeuchi, and I. G. Scheblykin. Chem. Mater., 2014, 26, 4867–4875.

Download references

Funding

The work was supported by the Russian Science Foundation (grant No. 18-13-00203).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Dubskikh, A. A. Lysova, D. G. Samsonenko, A. A. Ryadun, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  3. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Samsonov

Authors
  1. V. A. Dubskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Lysova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. G. Samsonenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Samsonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Ryadun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. N. Dybtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. P. Fedin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. P. Fedin.

Ethics declarations

The authors declare that they have no conflict of interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dubskikh, V.A., Lysova, A.A., Samsonenko, D.G. et al. STRUCTURE AND LUMINESCENT PROPERTIES OF COORDINATION POLYMERS CONTAINING LEAD(II) AND THIOPHENE LIGANDS. J Struct Chem 61, 1800–1809 (2020). https://doi.org/10.1134/S002247662011013X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247662011013X

Keywords

Search

Navigation