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Crystal structure of Ir(III) complexes with 1,10-phenanthroline: K[Ir(phen)Cl4]·H2O and (Me4N)[Ir(phen)Cl4]

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Abstract

The crystal structure of two salts of the complex [Ir(phen)Cl4]− anion with K+ (K[Ir(phen)Cl4]·H2O, 1) and Me4N+ ((Me4N)[Ir(phen)Cl4], 2) cations is determined. The iridium(III) ion is in a distorted octahedral environment consisting of chloride anions and a bidentate heterocyclic ligand of 1,10-phenanthroline (phen). A crucial role in the formation of the crystal structure of complex 1 belongs to K…Cl contacts, while in the crystal structure of complex 2, the stacking interactions dominate.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Adonin & P. A. Abramov

  2. Novosibirsk State University, Novosibirsk, Russia

    S. A. Adonin, P. A. Abramov & S. I. Uskov

Authors
  1. S. A. Adonin
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  2. P. A. Abramov
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  3. S. I. Uskov
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Correspondence to P. A. Abramov.

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Original Russian Text © 2014 S. A. Adonin, P. A. Abramov, S. I. Uskov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 3, pp. 538–542, May–June, 2014.

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Adonin, S.A., Abramov, P.A. & Uskov, S.I. Crystal structure of Ir(III) complexes with 1,10-phenanthroline: K[Ir(phen)Cl4]·H2O and (Me4N)[Ir(phen)Cl4]. J Struct Chem 55, 509–514 (2014). https://doi.org/10.1134/S0022476614030184

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  • DOI: https://doi.org/10.1134/S0022476614030184

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