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Effect of the synthesis technique on the physicochemical properties of Ce0.8(Sm0.75Sr0.2Ba0.05)0.2O2 − δ

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Abstract

A multicomponent solid electrolyte of composition Ce0.8(Sm0.75Sr0.2Ba0.05)0.2O2 − δ has been synthesized by three different techniques: solid-state reaction, laser evaporation, and the glycine nitrate process. Its microstructure, sintering kinetics, and electrical properties have been studied in relation to the synthesis technique. Ceramics produced using laser evaporation consisted of submicron (0.2 μm) grains and offered the highest electrical conductivity: 27 × 10−3 S/cm at 873 K.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    E. Yu. Pikalova, S. V. Plaksin & N. G. Molchanova

  2. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, ul. Amundsena 106, Yekaterinburg, 620016, Russia

    A. V. Nikonov, O. M. Samatov, A. S. Lipilin & V. R. Khrustov

  3. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620041, Russia

    V. D. Zhuravlev, V. G. Bamburov & I. V. Nikolaenko

Authors
  1. E. Yu. Pikalova
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  2. A. V. Nikonov
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  3. V. D. Zhuravlev
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  4. V. G. Bamburov
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  5. O. M. Samatov
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  6. A. S. Lipilin
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  7. V. R. Khrustov
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  8. I. V. Nikolaenko
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  9. S. V. Plaksin
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  10. N. G. Molchanova
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Corresponding author

Correspondence to E. Yu. Pikalova.

Additional information

Original Russian Text © E.Yu. Pikalova, A.V. Nikonov, V.D. Zhuravlev, V.G. Bamburov, O.M. Samatov, A.S. Lipilin, V.R. Khrustov, I.V. Nikolaenko, S.V. Plaksin, N.G. Molchanova, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 4, pp. 452–457.

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Pikalova, E.Y., Nikonov, A.V., Zhuravlev, V.D. et al. Effect of the synthesis technique on the physicochemical properties of Ce0.8(Sm0.75Sr0.2Ba0.05)0.2O2 − δ . Inorg Mater 47, 396–401 (2011). https://doi.org/10.1134/S0020168511040170

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  • DOI: https://doi.org/10.1134/S0020168511040170

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