Skip to main content
Log in

Microstructure and strength of carbon fibers surface-modified with titanium carbide

  • Published:
Inorganic Materials Aims and scope

Abstract

Continuous titanium carbide barrier coatings have been grown on UKN-5000 and VMN-4 carbon fibers using chemical vapor transport. The surface morphology and microstructure of as-received and TiC-coated fibers have been studied by scanning electron microscopy. The coating process is shown to raise the tensile strength and Weibull modulus of the fibers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Carbon Fibers and Their Composites, Fitzer, E., Ed., New York: Springer, 1986.

    Google Scholar 

  2. Uglerodnye volokna (Carbon Fibers), Simamura, S., Ed., Moscow: Mir, 1987 (translated from Japanese).

    Google Scholar 

  3. Donnet, J.B. and Ehrburger, P., Carbon Fibre in Polymer Reinforcement, Carbon, 1977, vol. 15, no. 1, pp. 143–152.

    Article  CAS  Google Scholar 

  4. Clark, D., Wadsworth, N.J., and Wart, W., Carbon Fibres, Plast. Polym. Conf. Suppl., 1974, no. 6, pp. 44–51.

  5. Handbook of Composites, Lubin, G., Ed., New York: Van Nostrand Reinhold, 1982, vol. 1.

    Google Scholar 

  6. Dhakate, S.R. and Bahl, O.P., Effect of Carbon Fiber Surface Functional Groups on the Mechanical Properties of Carbon-Carbon Composites with HTT, Carbon, 2003, vol. 41, no. 6, pp. 1193–1203.

    Article  CAS  Google Scholar 

  7. Zielke, U., Huttinger, K.J., and Hoffman, W.P., Surface-Oxidized Carbon Fibers: I. Surface Structure and Chemistry, Carbon, 1996, vol. 34, no. 8, pp. 983–998.

    Article  CAS  Google Scholar 

  8. Zielke, U., Huttinger, K.J., and Hoffman, W.P., Surface-Oxidized Carbon Fibers: III. Characterization of Carbon Fibers Surfaces by the Work of Adhesion/Ph Diagrams, Carbon, 1996, vol. 34, no. 8, pp. 1007–1013.

    Article  CAS  Google Scholar 

  9. Takao, Y., Kojima, A., Otani, S., and Yasuda, E., Changes in Color and Dynamic Viscoelastic Properties of Epoxy Resin Composites by Surface Modification of Carbon Fibres, Tanso, 1996, vol. 173, pp. 148–153.

    Google Scholar 

  10. Helmer, T., Petrlik, H., and Kromp, K., Coating of Carbon Fiber—The Strength of the Fibers, J. Am. Ceram. Soc., 1995, vol. 78, no. 1, pp. 133–136.

    Article  CAS  Google Scholar 

  11. Labruquere, S., Bourrat, X., Pailler, R., and Naslain, R., Structure and Oxidation of C/C Composites: Role of the Interface, Carbon, 2001, vol. 39, no. 7, pp. 971–984.

    Article  CAS  Google Scholar 

  12. Aggour, L., Fitzer, E., Ignatowitz, E., and Sanebkar, M., Chemical Vapour Deposition of Pyro-Carbon, SiC, TiC, Si, and Ta on Different Types of Carbon Fibres, Carbon, 1974, vol. 12, no. 3, pp. 358–362.

    Article  CAS  Google Scholar 

  13. Kusakabe, K., Sea, B.-K., Hayashi, J.-I., et al., Coating of Carbon Fibers with Amorphous SiC Films As Diffusion Barriers by Chemical Vapour Deposition with Triisopropylsilane, Carbon, 1996, vol. 34, no. 2, pp. 179–185.

    Article  CAS  Google Scholar 

  14. Beinborn, K.-M., Muller, M., and Huttinger, K.J., The Significance of the Fibre Coating in the Production of Carbon Fibre-Reinforced Carbons from HT Carbon Fibres: 1. Poly(dimethylsiloxane) and Poly(methylphenylsiloxane) Coatings, Carbon, 1995, vol. 33, no. 8, pp. 1029–1042.

    Article  CAS  Google Scholar 

  15. Baklanova, N.I., Zima, T.M., Boronin, A.I., et al., Protective Ceramic Multilayer Coatings for Carbon Fibers, Surf. Coat. Technol., 2006, vol. 201, no. 6, pp. 2313–2319.

    Article  CAS  Google Scholar 

  16. Baklanova, N.I., Kulyukin, V., and Zima, T., Formation of Refractory Coatings on Carbon-Based Materials by Gas-Phase Transport Reactions, Proc. 7th ADC/FCT (Japan), 2003, pp. 367–371.

  17. Baklanova, N.I., Kulyukin, V.N., Tatarintseva, M.I., et al., Growth of Tantalum Carbide Coatings on Carbon Fibers by Chemical Vapor Transport, in Zharostoikie neorganicheskie pokrytiya (High-Temperature Inorganic Coatings), Leningrad: Nauka, 1990, pp. 199–203.

    Google Scholar 

  18. Shafer, H., Chemical Transport as a Preparative Method, Preparative Methods in Solid State Chemistry, Hagenmuller, P., Ed., New York: Academic, 1972. Translated under the title Preparativnye metody v khimii tverdogo tela, Moscow: Mir, 1976, pp. 277–304.

    Google Scholar 

  19. Cheremskoi, P.G., Metody issledovaniya poristosti tverdykh tel (Techniques for Measuring the Porosity of Solids), Palatnik, L.S., Ed., Moscow: Energoatomizdat, 1985.

    Google Scholar 

  20. Baranov, A.V., Bekhterev, A.N., Bobovich, Ya.S., and Petrov, V.I., Interpretation of Some Features in the Raman Spectra of Graphite and Glassy Carbon, Opt. Spektrosk., 1987, vol. 62, no. 5, pp. 1036–1042.

    CAS  Google Scholar 

  21. Wang, Y., Alsmeyer, D.C., and McCreery, R.L., Raman Spectroscopy of Carbon Materials: Structural Basis of Observed Spectra, Chem. Mater., 1990, vol. 2, no. 5, pp. 557–563.

    Article  CAS  Google Scholar 

  22. Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, 1998.

  23. Rakov, E.G., Fluoride Metallurgy, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1987, vol. 30, no. 4, pp. 3–19.

    CAS  Google Scholar 

  24. Nickl, J.J., Koukoussas, J.D., and Muhlratzer, A., Untersuchung uber den isothermen chemischen Transport, J. Less-Common Met., 1973, vol. 32, no. 2, pp. 243–273.

    Article  CAS  Google Scholar 

  25. Barkovskii, N.V. and Tsirel’nikov, V.I., Termodinamicheskii raschet ravnovesnogo sostava sistemy Zr-ZrF 4 (Thermodynamic Evaluation of the Equilibrium Composition of the Zr-ZrF4 System), Available from VINITI, 1986, Moscow, no. 6849-13, p. 14.

  26. Gusev, A.I., Phase Equilibria, Phases, and Compounds in the Ti-S System, Usp. Khim., 2002, vol. 71, no. 6, pp. 507–532.

    Google Scholar 

  27. Fracassi, F. and d’Agostino, R., Chemistry of Titanium Dry Etching in Fluorinated and Chlorinated Gases, Pure Appl. Chem., 1992, vol. 64, no. 5, pp. 703–707.

    Article  CAS  Google Scholar 

  28. Baklanova, N.I. and Kulyukin, V.N., Some Features of Chemical Transport in the Ta-TaS-SiO2-Cl System, Izv. Akad. Nauk SSSR, Neorg. Mater., 1990, vol. 26, no. 1, pp. 97–101.

    CAS  Google Scholar 

  29. Himbeault, D.D., Varin, R.A., and Piekarski, K., Carbon Fibres Coated with Titanium Carbide Using the Liquid Metal Transfer Agent Technique, J. Mater. Sci., 1989, vol. 24, no. 12, pp. 2746–2750.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. I. Baklanova.

Additional information

Original Russian Text © N.I. Baklanova, T.M. Zima, A.T. Titov, T.M. Naimushina, V.P. Berveno, 2008, published in Neorganicheskie Materialy, 2008, Vol. 44, No. 2, pp. 162–170.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baklanova, N.I., Zima, T.M., Titov, A.T. et al. Microstructure and strength of carbon fibers surface-modified with titanium carbide. Inorg Mater 44, 121–128 (2008). https://doi.org/10.1134/S0020168508020076

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168508020076

Keywords

Navigation