Abstract
Continuous titanium carbide barrier coatings have been grown on UKN-5000 and VMN-4 carbon fibers using chemical vapor transport. The surface morphology and microstructure of as-received and TiC-coated fibers have been studied by scanning electron microscopy. The coating process is shown to raise the tensile strength and Weibull modulus of the fibers.
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References
Carbon Fibers and Their Composites, Fitzer, E., Ed., New York: Springer, 1986.
Uglerodnye volokna (Carbon Fibers), Simamura, S., Ed., Moscow: Mir, 1987 (translated from Japanese).
Donnet, J.B. and Ehrburger, P., Carbon Fibre in Polymer Reinforcement, Carbon, 1977, vol. 15, no. 1, pp. 143–152.
Clark, D., Wadsworth, N.J., and Wart, W., Carbon Fibres, Plast. Polym. Conf. Suppl., 1974, no. 6, pp. 44–51.
Handbook of Composites, Lubin, G., Ed., New York: Van Nostrand Reinhold, 1982, vol. 1.
Dhakate, S.R. and Bahl, O.P., Effect of Carbon Fiber Surface Functional Groups on the Mechanical Properties of Carbon-Carbon Composites with HTT, Carbon, 2003, vol. 41, no. 6, pp. 1193–1203.
Zielke, U., Huttinger, K.J., and Hoffman, W.P., Surface-Oxidized Carbon Fibers: I. Surface Structure and Chemistry, Carbon, 1996, vol. 34, no. 8, pp. 983–998.
Zielke, U., Huttinger, K.J., and Hoffman, W.P., Surface-Oxidized Carbon Fibers: III. Characterization of Carbon Fibers Surfaces by the Work of Adhesion/Ph Diagrams, Carbon, 1996, vol. 34, no. 8, pp. 1007–1013.
Takao, Y., Kojima, A., Otani, S., and Yasuda, E., Changes in Color and Dynamic Viscoelastic Properties of Epoxy Resin Composites by Surface Modification of Carbon Fibres, Tanso, 1996, vol. 173, pp. 148–153.
Helmer, T., Petrlik, H., and Kromp, K., Coating of Carbon Fiber—The Strength of the Fibers, J. Am. Ceram. Soc., 1995, vol. 78, no. 1, pp. 133–136.
Labruquere, S., Bourrat, X., Pailler, R., and Naslain, R., Structure and Oxidation of C/C Composites: Role of the Interface, Carbon, 2001, vol. 39, no. 7, pp. 971–984.
Aggour, L., Fitzer, E., Ignatowitz, E., and Sanebkar, M., Chemical Vapour Deposition of Pyro-Carbon, SiC, TiC, Si, and Ta on Different Types of Carbon Fibres, Carbon, 1974, vol. 12, no. 3, pp. 358–362.
Kusakabe, K., Sea, B.-K., Hayashi, J.-I., et al., Coating of Carbon Fibers with Amorphous SiC Films As Diffusion Barriers by Chemical Vapour Deposition with Triisopropylsilane, Carbon, 1996, vol. 34, no. 2, pp. 179–185.
Beinborn, K.-M., Muller, M., and Huttinger, K.J., The Significance of the Fibre Coating in the Production of Carbon Fibre-Reinforced Carbons from HT Carbon Fibres: 1. Poly(dimethylsiloxane) and Poly(methylphenylsiloxane) Coatings, Carbon, 1995, vol. 33, no. 8, pp. 1029–1042.
Baklanova, N.I., Zima, T.M., Boronin, A.I., et al., Protective Ceramic Multilayer Coatings for Carbon Fibers, Surf. Coat. Technol., 2006, vol. 201, no. 6, pp. 2313–2319.
Baklanova, N.I., Kulyukin, V., and Zima, T., Formation of Refractory Coatings on Carbon-Based Materials by Gas-Phase Transport Reactions, Proc. 7th ADC/FCT (Japan), 2003, pp. 367–371.
Baklanova, N.I., Kulyukin, V.N., Tatarintseva, M.I., et al., Growth of Tantalum Carbide Coatings on Carbon Fibers by Chemical Vapor Transport, in Zharostoikie neorganicheskie pokrytiya (High-Temperature Inorganic Coatings), Leningrad: Nauka, 1990, pp. 199–203.
Shafer, H., Chemical Transport as a Preparative Method, Preparative Methods in Solid State Chemistry, Hagenmuller, P., Ed., New York: Academic, 1972. Translated under the title Preparativnye metody v khimii tverdogo tela, Moscow: Mir, 1976, pp. 277–304.
Cheremskoi, P.G., Metody issledovaniya poristosti tverdykh tel (Techniques for Measuring the Porosity of Solids), Palatnik, L.S., Ed., Moscow: Energoatomizdat, 1985.
Baranov, A.V., Bekhterev, A.N., Bobovich, Ya.S., and Petrov, V.I., Interpretation of Some Features in the Raman Spectra of Graphite and Glassy Carbon, Opt. Spektrosk., 1987, vol. 62, no. 5, pp. 1036–1042.
Wang, Y., Alsmeyer, D.C., and McCreery, R.L., Raman Spectroscopy of Carbon Materials: Structural Basis of Observed Spectra, Chem. Mater., 1990, vol. 2, no. 5, pp. 557–563.
Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, 1998.
Rakov, E.G., Fluoride Metallurgy, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1987, vol. 30, no. 4, pp. 3–19.
Nickl, J.J., Koukoussas, J.D., and Muhlratzer, A., Untersuchung uber den isothermen chemischen Transport, J. Less-Common Met., 1973, vol. 32, no. 2, pp. 243–273.
Barkovskii, N.V. and Tsirel’nikov, V.I., Termodinamicheskii raschet ravnovesnogo sostava sistemy Zr-ZrF 4 (Thermodynamic Evaluation of the Equilibrium Composition of the Zr-ZrF4 System), Available from VINITI, 1986, Moscow, no. 6849-13, p. 14.
Gusev, A.I., Phase Equilibria, Phases, and Compounds in the Ti-S System, Usp. Khim., 2002, vol. 71, no. 6, pp. 507–532.
Fracassi, F. and d’Agostino, R., Chemistry of Titanium Dry Etching in Fluorinated and Chlorinated Gases, Pure Appl. Chem., 1992, vol. 64, no. 5, pp. 703–707.
Baklanova, N.I. and Kulyukin, V.N., Some Features of Chemical Transport in the Ta-TaS-SiO2-Cl System, Izv. Akad. Nauk SSSR, Neorg. Mater., 1990, vol. 26, no. 1, pp. 97–101.
Himbeault, D.D., Varin, R.A., and Piekarski, K., Carbon Fibres Coated with Titanium Carbide Using the Liquid Metal Transfer Agent Technique, J. Mater. Sci., 1989, vol. 24, no. 12, pp. 2746–2750.
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Original Russian Text © N.I. Baklanova, T.M. Zima, A.T. Titov, T.M. Naimushina, V.P. Berveno, 2008, published in Neorganicheskie Materialy, 2008, Vol. 44, No. 2, pp. 162–170.
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Baklanova, N.I., Zima, T.M., Titov, A.T. et al. Microstructure and strength of carbon fibers surface-modified with titanium carbide. Inorg Mater 44, 121–128 (2008). https://doi.org/10.1134/S0020168508020076
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DOI: https://doi.org/10.1134/S0020168508020076