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Crystal structure of the Lanthanum(III) complex [La(DMSO)6(H2O)PW12O40] · C2H5OH (DMSO is dimethyl sulfoxide)

  • Structure of Organic Compounds
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Abstract

The crystal structure of the [La(DMSO)6(H2O)PW12O40] · C2H5OH complex (I) (where DMSO is dimethyl sulfoxide) is determined by X-ray diffraction analysis. The coordination polyhedron of the La atom is a distorted tricapped trigonal prism in which two cap sites are occupied by oxygen atoms of the heteropolyanions. For these atoms, the La-O distances [2.760(9) and 2.801(9) Å] are considerably longer than the other distances [ranging from 2.441(10) to 2.569(10) Å] in the environment of the La atom.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    M. S. Grigoriev, I. B. Shirokova & A. M. Fedoseev

  2. Commissariat of Atomic Energy of France, France

    C. Den Auwer

Authors
  1. M. S. Grigoriev
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  2. I. B. Shirokova
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  3. A. M. Fedoseev
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  4. C. Den Auwer
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Translated from Kristallografiya, Vol. 47, No. 6, 2002, pp. 1039–1041.

Original Russian Text Copyright © 2002 by Grigoriev, Shirokova, Fedoseev, Den Auwer.

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Grigoriev, M.S., Shirokova, I.B., Fedoseev, A.M. et al. Crystal structure of the Lanthanum(III) complex [La(DMSO)6(H2O)PW12O40] · C2H5OH (DMSO is dimethyl sulfoxide). Crystallogr. Rep. 47, 970–972 (2002). https://doi.org/10.1134/1.1523543

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  • DOI: https://doi.org/10.1134/1.1523543

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