Abstract
The IR absorption spectra of solutions of SF6 in liquid argon are studied at a temperature of 93 K in the concentration interval 10−5–10−7 mole fractions. A sample with a natural abundance of isotopes and a monoisotope 34SF6 sample are studied. The frequencies, half-widths, and relative intensities of bands in the vibrational spectrum of all isotopomers of the molecule are determined. For the 34SF6 molecule, the ratio of integral absorption coefficients of fundamental bands A(ν4)/A(ν3)=0.07(6) is larger than 32SF6:A(ν4)/A(ν3)=0.66(4) for the 32SF6 molecule, which corresponds to the same signs of P′3 and P′4. The change in the intensity of the ν2+ν6 and ν5+ν6 bands upon isotopic substitution is explained by the change in the resonance contributions of due to the isotope shift of the ν3 band.
Similar content being viewed by others
References
Advances in Spectroscopy, Vol. 23: Molecular Cryospectroscopy, Ed. by R. J. H. Clark and R. E. Hester (Wiley, Chichester, 1995).
V. V. Bertsev, M. O. Bulanin, and T. D. Kolomiĭtsova, Opt. Spektrosk. 35, 277 (1973).
C. Chapados and G. Birnbaum, J. Mol. Spectrosc. 132, 323 (1988).
T. D. Kolomiĭtsova, S. M. Melikova, and D. N. Shchepkin, Opt. Spektrosk. 60, 1165 (1986) [Opt. Spectrosc. 60, 722 (1986)].
S. M. Melikova and D. N. Shchepkin, Opt. Spektrosk. 53, 1019 (1982) [Opt. Spectrosc. 53, 609 (1982)].
S. M. Melikova, Author’s Abstract of Candidate’s Dissertation (Leningr. Gos. Univ., Leningrad, 1988).
P. N. Schatz and D. F. Hornig, J. Chem. Phys. 21, 1516 (1953).
J. H. Schachtschneider, D. Sc. Dissertation (Univ. of Minnesota, 1960).
W. B. Person and K. C. Kim, J. Chem. Phys. 69, 1764 (1978).
K. C. Kim, R. McDowell, and W. T. King, J. Chem. Phys. 73, 36 (1980).
C. Brodbeck, I. Rossi, H. Strapelias, and J.-P. Bouanich, Chem. Phys. 54, 1 (1980).
D. S. Dunn, K. Scanlon, and J. Overend, Spectrochim. Acta A 38, 841 (1982).
S. Chin and W. B. Person, J. Mol. Spectrosc. 98, 258 (1983).
M. O. Bulanin, A. P. Burtsev, Yu. M. Ladvishchenko, and K. Kerl, Mol. Phys. 97, 1233 (1999).
N. E. Holden, R. L. Martin, and I. L. Barnes, Pure Appl. Chem. 56, 675 (1984).
V. V. Bertsev, T. D. Kolomiĭtsova, and N. M. Tsyganenko, Opt. Spektrosk. 37, 463 (1974).
A. Vinit, J. Lambard, P. Nectoux, and M. Gilbert, Chem. Phys. Lett. 63, 460 (1979).
S. R. J. Brueck, T. F. Deutsch, and R. M. Osgood, Jr., Chem. Phys. Lett. 60, 242 (1979).
T. A. Beu and K. Takeuchi, J. Chem. Phys. 103, 6394 (1995).
V. Boudon, M. Hepp, M. Herman, et al., J. Mol. Spectrosc. 192, 359 (1998).
V. D. Klimov and E. A. Lobikov, Opt. Spektrosk. 30, 48 (1971).
W. B. Person and B. J. Krohn, J. Mol. Spectrosc. 98, 229 (1983).
T. D. Kolomiĭtsova and D. N. Shchepkin, Opt. Spektrosk. 38, 51 (1975) [Opt. Spectrosc. 38, 28 (1975)].
B. J. Krohn and J. Overend, J. Phys. Chem. 88, 564 (1984).
Author information
Authors and Affiliations
Additional information
__________
Translated from Optika i Spektroskopiya, Vol. 92, No. 4, 2002, pp. 564–568.
Original Russian Text Copyright © 2002 by Kolomiĭtsova, Kondaurov, Sedelkova, Shchepkin.
Rights and permissions
About this article
Cite this article
Kolomiĭtsova, T.D., Kondaurov, V.A., Sedelkova, E.V. et al. Isotope effects in the vibrational spectrum of the SF6 molecule. Opt. Spectrosc. 92, 512–516 (2002). https://doi.org/10.1134/1.1473589
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1473589